Comparison of single- and multivariate calibration for determination of Si, Mn, Cr and Ni in high-alloyed stainless steels by laser-induced breakdown spectrometry

Zaytsev, Sergey M.; Popov, A. M.; Chernykh, E. V.; Voronina, R. D.; Зоров, Н. Б.; Лабутин, Т.А.

doi:10.1039/c3ja50389e

Cited by 41 publications

(13 citation statements)

References 25 publications

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“…At room temperature, Li 15 Si 4 has been proposed as the fully lithiated phase of Si, leading to a maximum capacity of 3579 mAh g −1 and a volume expansion of 280% . The discharge and charge potentials of Si are ≈0.2 and 0.3–0.5 V with respect to Li/Li + , respectively.…”

Section: Si For Libsmentioning

confidence: 99%

Group IVA Element (Si, Ge, Sn)‐Based Alloying/Dealloying Anodes as Negative Electrodes for Full‐Cell Lithium‐Ion Batteries

Liu

et al. 2017

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To satisfy the increasing energy demands of portable electronics, electric vehicles, and miniaturized energy storage devices, improvements to lithium‐ion batteries (LIBs) are required to provide higher energy/power densities and longer cycle lives. Group IVA element (Si, Ge, Sn)‐based alloying/dealloying anodes are promising candidates for use as electrodes in next‐generation LIBs owing to their extremely high gravimetric and volumetric capacities, low working voltages, and natural abundances. However, due to the violent volume changes that occur during lithium‐ion insertion/extraction and the formation of an unstable solid electrolyte interface, the use of Group IVA element‐based anodes in commercial LIBs is still a great challenge. Evaluating the electrochemical performance of an anode in a full‐cell configuration is a key step in investigating the possible application of the active material in LIBs. In this regard, the recent progress and important approaches to overcoming and alleviating the drawbacks of Group IVA element‐based anode materials are reviewed, such as the severe volume variations during cycling and the relatively brittle electrode/electrolyte interface in full‐cell LIBs. Finally, perspectives and future challenges in achieving the practical application of Group IVA element‐based anodes in high‐energy and high‐power‐density LIB systems are proposed.

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Section: Si For Libsmentioning

confidence: 99%

Group IVA Element (Si, Ge, Sn)‐Based Alloying/Dealloying Anodes as Negative Electrodes for Full‐Cell Lithium‐Ion Batteries

Liu

et al. 2017

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“…Therefore, it is reported that LIBS has suffered the influence of self-absorption, which caused a decrease in the slope of the calibration curve. 37,44,45 Obviously, the measurement results are less affected by self-absorption using long–short DP-LIBS. It can be attributed to the stabilization effect of a long pulse.…”

Section: Calibration Curvesmentioning

confidence: 99%

Improved Analysis of Manganese in Steel Samples Using Collinear Long–Short Double Pulse Laser-Induced Breakdown Spectroscopy (LIBS)

et al. 2018

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A long-short double pulse laser-induced breakdown spectroscopy (long-short DP-LIBS) method was employed to improve the analytical performance of LIBS for the measurement of manganese in steel samples. The long pulse with a duration of 60 μs was generated using a neodymium-doped yttrium aluminum garnet (Nd:YAG) laser which was operated at free-running (FR) mode. To investigate the detection ability without sample preparation, the steel washers were tested using single-pulse LIBS (SP-LIBS) and long-short DP-LIBS, respectively. The measurement results show that long-short DP-LIBS was able to record clear spectra from the steel washers with a surface layer. Through the observation on the laser craters with a scanning electron microscope (SEM), the results suggest that the improvement in detection ability can be attributed to the pre-irradiation effect of long-pulse laser beam. Next, the analytical performance for quantitative measurement of manganese was evaluated employing ten standard steel samples. The results show that the linearity fit (R) of the calibration curve is 0.988 for long-short DP-LIBS, whereas, R is only 0.810 for SP-LIBS under the same measurement conditions. The repeated measurement results show that the average relative standard deviation (RSD) of the tested samples is 29.3% for SP-LIBS and is 10.5% for long-short DP-LIBS. The prediction results also show that the average relative error of prediction (REP) is 94.9% for SP-LIBS and is 4.9% for long-short DP-LIBS.

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“…The input variable of PLS can be characteristic spectral lines [42], partial spectral region [43] or full spectrum [44]. Amador-Hernandez et al [45] used PLS-1 to quantify gold and silver gold and silver in Au-Ag-Cu alloys.…”

Section: Calibration and Validation Of Analytical Methods -A Samplingmentioning

confidence: 99%

Calibration Methods of Laser-Induced Breakdown Spectroscopy

Fu¹,

Jia²,

Wang³

et al. 2018

Calibration and Validation of Analytical Methods - A Sampling of Current Approaches

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Laser-induced breakdown spectroscopy (LIBS) has gained great attention over the past two decades due to its many advantages, such as needless sample preparation, capability of remote measurement and fast multielement simultaneous analysis. However, because of its inherent uncertainty features of plasma, it is still a big challenge for LIBS community worldwide to realize high sensitivity and accurate quantitative analysis. Currently, many chemometric analytical methods have been applied to LIBS calibration analysis, including univariate regression, multivariate regression, principal component regression (PCR), partial least squares regression (PLSR) and so on. In addition, appropriate sample and spectral pretreatment can effectively improve the analytical performance (i.e., limit of detection (LOD), accuracy and repeatability) of LIBS. In this chapter, we briefly summarize the progress of these calibration methods and their applications on LIBS and provide our recommendations.

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Comparison of single- and multivariate calibration for determination of Si, Mn, Cr and Ni in high-alloyed stainless steels by laser-induced breakdown spectrometry

Abstract: Overcoming the matrix effect in LIBS analysis of high-alloyed stainless steel by specifying the temporal parameters of signal registration and multivariate calibration based on PCR.

Cited by 41 publications

References 25 publications

Group IVA Element (Si, Ge, Sn)‐Based Alloying/Dealloying Anodes as Negative Electrodes for Full‐Cell Lithium‐Ion Batteries

Group IVA Element (Si, Ge, Sn)‐Based Alloying/Dealloying Anodes as Negative Electrodes for Full‐Cell Lithium‐Ion Batteries

Improved Analysis of Manganese in Steel Samples Using Collinear Long–Short Double Pulse Laser-Induced Breakdown Spectroscopy (LIBS)

Calibration Methods of Laser-Induced Breakdown Spectroscopy

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