Complex-radical terpolymerization of acceptor-donor-acceptor systems: Maleic anhydride (n-butyl methacrylate)-styrene-acrylonitrile

Medyakova, L.V.; Rzaev, Zakır M. O.; Güner, Ali̇; Ki̇barer, Günay

doi:10.1002/1099-0518(20000801)38:15<2652::aid-pola40>3.0.co;2-b

Cited by 11 publications

(4 citation statements)

References 29 publications

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“…A search of literature revealed that most of the work has been devoted to the terpolymerization of three vinyl monomers, such as poly(ethylene glycol) ethylether methacrylate‐ co ‐methacrylic acid‐ co ‐sodium styrene sulfonate,1 methyl methacrylate (MMA)‐ co ‐acrylonitrile‐ co ‐4‐vinylpyridine and styrene (Sty),2 maleic anhydride–( n ‐butyl methacrylate)–Sty–acrylonitrile,3 acrylamide–acrylic acid–acrylonitrile,4 Sty–vinylpyrrolidone–acrylonitrile,5 Sty–acrylonitrile–copperacrylate,6 and Sty–acrylonitrile–chromium acrylate 7. However, reports regarding the synthesis of terpolymers containing a terpene as one of the monomers are scarce, except for a few recent contributions from our laboratory, such as for the syntheses of citronellol–Sty–MMA/benzoyl peroxide (BPO)/80°C8 and linalool–Sty–MMA/BPO/80°C 9.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and characterization of a terpolymer of limonene, styrene, and methyl methacrylate via a free‐radical route

Sharma

Srivastava

2003

J of Applied Polymer Sci

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ABSTRACT:The free-radical terpolymerization of a monocyclic terpene, namely, limonene (Lim), with styrene (Sty) and methyl methacrylate (MMA) in xylene at 80 Ϯ 0.1°C for 2 h, with benzoyl peroxide (BPO) as an initiator under an inert atmosphere of nitrogen was extensively studied. H-NMR spectra showed peaks at 7.3-8.1, 3.9 -4.4, and 5.0 -5.5 ␦ due to the phenyl, methoxy, and trisubstituted olefinic protons of Sty, MMA and Lim, respectively. The values of the reactivity ratios r 1 (MMA; 0.33) and r 2 (Sty ϩ Lim; 0.06) were calculated with the Kelen-T udos method.

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Section: Introductionmentioning

confidence: 99%

Synthesis and characterization of a terpolymer of limonene, styrene, and methyl methacrylate via a free‐radical route

Sharma

Srivastava

2003

J of Applied Polymer Sci

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“…In this model, it has been assumed that the radical reactivity is only a function of their end units (i.e., terminal model) and penultimate effect is negligible. Although MAh can generate chargetransfer complexes with St and MMA [4][5][6][7][8][9] the use of a terminal model is in part justified because at high temperatures the donoracceptor complex concentrations should be extremely small. [10] From the reactions listed in Table 1, species molar balances in a generic isothermal CSTR are derived.…”

Section: Chemical Initiationmentioning

confidence: 99%

Mathematical Modeling of Free Radical Solution Terpolymerization Reactions in a Batch and Continuous Flow Stirred Tank Reactors

Luciani

Choi

2021

Macro Theory & Simulations

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The ORCID identification number(s) for the author(s) of this article can be found under https://doi.org/10.1002/mats.202000094.A mathematical model that describes a free radical solution terpolymerization is applied to styrene (St), methyl methacrylate (MMA), and maleic anhydride (MAh) polymerization system. This terpolymerization model allows for the use of either monofunctional or bifunctional peroxide initiators, and it is applied to batch and continuous reactions. The key model outputs are global monomer conversion, terpolymer composition, terpolymer average molecular weights, and terpolymer monomer sequence distributions. A few kinetic parameters are estimated such that global conversion is properly predicted by the model including initiator efficiency and two termination rate constants. Molecular weights are shown to be dominated by chain transfer reactions. Experimental trends of conversion, terpolymer molar masses (molecular weights), and composition are reasonably well predicted by the model.

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“…Complex‐radical copolymerization of electron‐donor and electron‐acceptor binary and ternary monomer systems is an effective method for the synthesis of functional macromolecules with given composition, structure, and properties 12–18. In some earlier publications, a number of systematic studies were carried out for the terpolymerization of maleic anhydride, styrene, and donor‐ or acceptor‐type monomers such as unsaturated epoxides,18 acrylics,19, 20 citraconic anhydride,21 certain maleimides,22 and N ‐vinyl pyrrolidone 23…”

Section: Introductionmentioning

confidence: 99%

Functional terpolymers containing vinylphosphonic acid: The synthesis and characterization of poly(vinylphosphonic acid‐co‐styrene‐co‐maleic anhydride)

Kavlak¹,

Güner²,

Rzayev³

2012

J of Applied Polymer Sci

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Novel functional temperature-sensitive amphiphilic P-containing polymers were synthesized by complex-radical ternary polymerization of vinylphosphonic acid (VPA), styrene (S), and maleic anhydride (MA). Charge transfer complexes (CTCs), complex-formation constants (K c ) between acceptor and donor monomer systems and the complexed monomer reactivity ratios were investigated by 1 H-NMR analysis. Contrary to theoretical predictions, the VPA. . .S complex is more active as compared to MA. . .S complex in the ternary system since VPA monomer can form the CTC both with S monomer and strong H-bonded complex with MA monomer. The terpolymer compositions, characterizations, and structureproperty relationships of a series of poly(VPA-co-S-co-MA)s were investigated by GPC, FTIR, Raman, 1 H-NMR, 13 C-NMR, DEPT-135, 31 P-NMR, TGA-DSC, DMA, XRD, viscometry, and titration.

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Complex-radical terpolymerization of acceptor-donor-acceptor systems: Maleic anhydride (n-butyl methacrylate)-styrene-acrylonitrile

Cited by 11 publications

References 29 publications

Synthesis and characterization of a terpolymer of limonene, styrene, and methyl methacrylate via a free‐radical route

Synthesis and characterization of a terpolymer of limonene, styrene, and methyl methacrylate via a free‐radical route

Mathematical Modeling of Free Radical Solution Terpolymerization Reactions in a Batch and Continuous Flow Stirred Tank Reactors

Functional terpolymers containing vinylphosphonic acid: The synthesis and characterization of poly(vinylphosphonic acid‐co‐styrene‐co‐maleic anhydride)

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