Phys. Chem. Chem. Phys.
 2025
DOI: 10.1039/d4cp03577a
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Comprehensive quantum chemical and mass spectrometric analysis of the McLafferty rearrangement of methyl valerate

Mitsuo Takayama,
Masahiro Hashimoto,
Keijiro Ohshimo
et al.

Abstract: The McLafferty rearrangement (McLR) of methyl valerate molecular ion has been comprehensively studied from the standpoint of the time scales for the keto-enol transformation and the dynamic change of the...

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