“…High pressure X-ray diffraction (HP-XRD) experiments [15], carried out on technological Nb 3 Sn wires, showed an anomaly in the unit cell volume compression (around 5 GPa) not associated with any structural phase transition. A similar effect, ascribed to isostructural transitions, was observed around 15 GPa for other A15 systems, e.g., Nb 3 Ga [18] and Nb 3 Al [19] . Whereas, low temperature (T = 10 K) HP-XRD measurements, performed on a slightly non stoichiometric Nb 3 Sn 1−x single crystal, have evidenced structural instabilities around 3 GPa, suggesting a dimerization of Nb-Nb chains, providing alternating shorter/longer Nb-Nb pairs [17].…”