2007
DOI: 10.1107/s0021889807002981
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Concentration fluctuations induced by orientation fluctuations in polybutadiene–4-cyano-4'-n-octylbiphenyl mixtures

Abstract: The changes in concentration fluctuations of polymer-liquid crystal (LC) binary mixtures with temperature were investigated by small-angle X-ray scattering in their one-phase region and in the isotropic state of the LC. The concentration fluctuations consist of two modes: an OZD mode expressed by the OrnsteinZernike-Debye equation with a correlation length and a DB mode expressed by the Debye-Buche equation with a correlation length l. The temperature dependence of the OZD mode exhibits critical phenomena simi… Show more

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