2001
DOI: 10.1016/s0927-7757(00)00761-5
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Conductance and viscosity studies of sodium dodecylsulfate in aqueous solutions of dimethylsulfoxide and methanol

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Cited by 45 publications
(15 citation statements)
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“…Fine-Chem. Ltd.) were dried on 4-Å molecular sieves for 24 h and were purified as reported in the literature [4,5]. Doubly distilled water was used in the entire work.…”
Section: Methodsmentioning
confidence: 99%
“…Fine-Chem. Ltd.) were dried on 4-Å molecular sieves for 24 h and were purified as reported in the literature [4,5]. Doubly distilled water was used in the entire work.…”
Section: Methodsmentioning
confidence: 99%
“…The results have been further explained on the basis of relative viscosity measurements [22][23][24][25]. Fig.…”
Section: Resultsmentioning
confidence: 82%
“…The changes in the absorption spectrum of solutes associated with the presence of micellar aggregates allow the discrimination between molecules in the different solubilization environments enabling the quantification of free or micelle-bound solute, whenever solute micellar binding/incorporation is accompanied by appropriate spectral shifts [14,27]. Sodium dodecyl sulfate critical micelle concentration (CMC) in the presence of MeOH (3%), and Tris buffer was determined through surface tension measurements, using a titrimetric procedure, and resorting to Gibbs equation (CMC ¼ 1.23 Â 10 À3 M) [32,36,[39][40][41]. The partition toward a micellar pseudo phase is described by a saturation curve, therefore, if the CMC is known, K p (K p ¼ x sulf,mic /x sulf,w ) where x sulf,w and x sulf,mic are equilibrium sulfenamide mole fractions in aqueous and micellar media) can be determined.…”
Section: Methodsmentioning
confidence: 99%