Conductive modifications of polymers with polypyrroles and polythiophenes

Jonas, Friedrich; Schrader, Lutz

doi:10.1016/0379-6779(91)91506-6

Cited by 367 publications

(195 citation statements)

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“…Since the first synthesis of poly(3,4-ethylenedioxythiophene) (PEDOT) in 1980 by Bayer [4], this polymer has been widely studied due to its high conductivity, interesting electrical and spectrochemical properties associated with its low band gap, as well as electrochromic and antistatic properties [5][6][7].…”

Section: Introductionmentioning

confidence: 99%

Highly sensitive poly(3,4-ethylenedioxythiophene) modified electrodes by electropolymerisation in deep eutectic solvents

Prathish

Carvalho

Brett

2014

Electrochemistry Communications

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Please cite this article as: Krishna P. Prathish, Ricardo C. Carvalho, Christopher M.A. Brett, Highly sensitive poly(3,4-ethylenedioxythiophene) modified electrodes by electropolymerisation in deep eutectic solvents, Electrochemistry Communications (2014Communications ( ), doi: 10.1016Communications ( /j.elecom.2014 This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain. A C C E P T E D M A N U S C R I P T ACCEPTED MANUSCRIPT AbstractDeep eutectic solvents are evaluated as media for the electropolymerisation of 3,4-ethylenedioxythiophene (EDOT) for the first time. PEDOT modified glassy carbon electrodes (GCE) were characterised by cyclic voltammetry, electrochemical impedance spectroscopy and scanning electron microscopy. PEDOT modified GCEs prepared from choline chloride-urea (reline) and choline chloride -ethylene glycol (ethaline) exhibited interesting electrocatalytic and morphological characteristics. Fixed potential sensing of ascorbate at 0.0 V showed a greater electrocatalytic effect, significantly higher sensitivity and lower detection limit than at hitherto reported PEDOT modified electrodes.

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Section: Introductionmentioning

confidence: 99%

Highly sensitive poly(3,4-ethylenedioxythiophene) modified electrodes by electropolymerisation in deep eutectic solvents

Prathish

Carvalho

Brett

2014

Electrochemistry Communications

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“…I XPS analysis at a 25 degree takeoff angle. 2 Modification procedures identical to those in Table I. …”

Section: Instrument-based Methods For Improving Conductive Polymer Admentioning

confidence: 99%

Modification of fluoropolymer surfaces with electronically conductive polymers

et al. 1994

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“…121,122 PEDOT possesses excellent chemical and thermal stability, unique electrochemical and spectroscopic properties, and inherently high conductivity. Consequently, it has been suggested for use in a wide range of applications, including antistatic coatings, capacitors, thin-film transistors, and electroluminescent and photovoltaic devices.…”

Section: Nanoporous Poly(34-ethylenedioxythiophene) (Pedot)mentioning

confidence: 99%

Nanocasting nanoporous inorganic and organic materials from polymeric bicontinuous microemulsion templates

Jones

Lodge

2012

Polym J

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Ternary blends of two homopolymers and a diblock copolymer can self-assemble into interpenetrating, three-dimensionally continuous networks with a characteristic length scale of B100 nm. In this review, we summarize our recent work demonstrating that these equilibrium fluid phases, known as polymeric bicontinuous microemulsions (BlE), can be designed as versatile precursors to nanoporous materials having pores with uniform sizes of B100 nm. As a model system, nanoporous polyethylene (PE) is derived from BlEs composed entirely of polyolefins. This monolithic material is then used as a template in the synthesis of other nanoporous materials for which structural control at the nm scale has traditionally been difficult to achieve. These materials, which include a high-temperature ceramic, polymeric thermosets and a conducting polymer, are produced by a simple nanocasting process, providing an inverse replica of the PE template. The PE is further used as a template for the production of hierarchically structured inorganic and polymeric materials by infiltration of mesostructured compounds into its pore network. The work described herein represents an unprecedented suite of nanoporous materials with well-defined pore structures prepared from a single PE template. They are anticipated to have potential application in diverse technological areas, including catalysis, separations and electronic devices.

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Conductive modifications of polymers with polypyrroles and polythiophenes

Cited by 367 publications

References 0 publications

Highly sensitive poly(3,4-ethylenedioxythiophene) modified electrodes by electropolymerisation in deep eutectic solvents

Highly sensitive poly(3,4-ethylenedioxythiophene) modified electrodes by electropolymerisation in deep eutectic solvents

Modification of fluoropolymer surfaces with electronically conductive polymers

Nanocasting nanoporous inorganic and organic materials from polymeric bicontinuous microemulsion templates

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