Construction and Evaluation of a Miniature Electron Ion Coincidence Analyzer Mounted on a Conflat Flange with an Outer Diameter of 114 mm

Kakiuchi, Takuhiro; Kobayashi, Eiichi; Okudaira, Koji K.; Fujita, Narihiko; Tanaka, Masatoshi; Mase, Kenji

doi:10.2116/analsci.24.87

Cited by 4 publications

(1 citation statement)

References 41 publications

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“…The mass of desorbed ions was analyzed by a TOF spectrometer coaxially installed within a cylindrical mirror analyzer (CMA) of electrons and ions emitted from the sample with specific energies. 28) To collect the desorbed ions, a voltage of À900 V was applied to the entrance slit of the TOF tube with respect to the sample. Ion desorption efficiency spectra were measured for total ions collected by the TOF tube of another analyzer of the same type but with less mass resolution.…”

Section: Experimental Methodsmentioning

confidence: 99%

Ion Desorption from Single-Walled Carbon Nanotubes Induced by Soft X-ray Illumination

Mera

Fujiwara

Ishizaki

et al. 2010

Jpn. J. Appl. Phys.

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We have investigated ion desorption from single-walled carbon nanotubes (SWNTs) that is induced by soft X-ray illumination in the C 1s core-excitation energy range in order to have insight to the mechanism of defect formation caused by the similar excitation. The mass of desorbed ions was analyzed by a time of flight (TOF) spectrometer and the photon energy 2 dependence of the ion yield or the desorption efficiency spectra were measured as a function of the monochromatic photon energy used for illumination. Experimental results exclude the simple detachment of carbon atoms constituting the nanotubes from the cause of the defect formation.Also the photo-induced etching of carbon atoms associated with C-H bond rapture is ruled out from the defect formation mechanism. Auger mechanisms to explain the photo-induced desorption are discussed.

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Section: Experimental Methodsmentioning

confidence: 99%

Ion Desorption from Single-Walled Carbon Nanotubes Induced by Soft X-ray Illumination

Mera

Fujiwara

Ishizaki

et al. 2010

Jpn. J. Appl. Phys.

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The formation of dinuclear trichloro-bridged and mononuclear ruthenium complexes from the reactions of dichlorotris(p-tolylphosphine)ruthenium(II) with diazabutadiene ligands

et al. 2018

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Ru(II) complexes with diazabutadiene (R-DAB) ligands have been prepared. The reaction of RuCl 3 •nH 2 O with P(p-tolyl) 3 gave a [RuCl 2 {P(p-tolyl) 3 }] precursor, whose reactions with R-DAB in toluene gave dinuclear trichloro-bridged Ru(II) complexes [Ru 2 Cl 3 (P(p-tolyl) 3 ) 2 (R-DAB) 2 ](BF 4 ) which have been characterized by spectroscopic methods. In addition, one of the complexes was characterized using X-ray crystallography. Meanwhile, two mononuclear Ru(II) complexes [RuCl 2 (P(p-tolyl) 3 ) 2 (R-DAB)] were obtained from the reactions of the [RuCl 2 {P(p-tolyl) 3 }] precursor with R-DAB ligands in THF. The two trans-mononuclear complexes were characterized by X-ray crystallography and solid-state 31 P NMR. A temperature-dependent 31 P NMR study was carried out to monitor the formation of dinuclear and mononuclear complexes.

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Development of a compact electron ion coincidence analyzer using a coaxially symmetric mirror electron energy analyzer and a miniature polar-angle-resolved time-of-flight ion mass spectrometer with four concentric anodes

Kobayashi

Nambu

Mase

et al. 2009

Review of Scientific Instruments

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A compact electron ion coincidence (EICO) analyzer that uses a coaxially symmetric mirror electron energy analyzer and a miniature polar-angle-resolved time-of-flight ion mass spectrometer with four concentric anodes was developed for surface science and surface analysis. The apparatus is especially useful in the study of ion desorption stimulated by an Auger process because information on the mass, yield, desorption polar angle, and kinetic energy of ions can be obtained for the selected core-ionization-final-states or the selected Auger-final-states. The analyzer can be used also for analysis of the configuration of specific surface molecules because the desorption polar angles reflect the direction of surface bonds. The EICO analyzer was evaluated by measuring polar-angle-resolved-ion yield spectra and coincidence spectra of Auger-electron and polar-angle-resolved H(+) from condensed water.

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Construction and Evaluation of a Miniature Electron Ion Coincidence Analyzer Mounted on a Conflat Flange with an Outer Diameter of 114 mm

Cited by 4 publications

References 41 publications

Ion Desorption from Single-Walled Carbon Nanotubes Induced by Soft X-ray Illumination

Ion Desorption from Single-Walled Carbon Nanotubes Induced by Soft X-ray Illumination

The formation of dinuclear trichloro-bridged and mononuclear ruthenium complexes from the reactions of dichlorotris(p-tolylphosphine)ruthenium(II) with diazabutadiene ligands

Development of a compact electron ion coincidence analyzer using a coaxially symmetric mirror electron energy analyzer and a miniature polar-angle-resolved time-of-flight ion mass spectrometer with four concentric anodes

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