Construction of an Optical Sensor for the Determination of Ascorbic Acid Using Ionic Liquids as Modifier

Absalan, Ghodratollah; Arabi, Maryam; Tashkhourian, Javad

doi:10.2116/analsci.28.1225

Cited by 5 publications

(5 citation statements)

References 36 publications

(31 reference statements)

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“…Its value was 0.0 up to 0.98 %. This RSD are higher when compared with other reported for determination AA-based optical sensor 19,20 . This show that optical chemical sensors have excellent reproducibility and repeatability, as shown in Figure 3.…”

Section: Response Optical Sensor For Colorimetric Measurements Of Ascorbic Acidmentioning

confidence: 52%

Transparent Membrane of Polyelectrolyte Complex Doped with 2,6-Dichlorophenol-Indophenol as an Optical Sensor for Colorimetric Measurements of Ascorbic acid

Hermanto¹,

Ismillayli²,

Honiar³

et al. 2020

Orient. J. Chem

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An optical chemical sensor based on a transparent membrane of polyelectrolyte complex (PEC), composed of alginate-chitosan membrane and 2,6-dichlorophenol-indophenol (2,6-DCPIP), coated on transparent mica was coupled with UV-Vis spectrophotometry and used for colorimetric measurements of ascorbic acid (AA). The transparent membranes of PEC were characterized using scanning electron microscopy (SEM) technique. The experimental parameters of the biosensor were optimized. Here, the optical chemical sensor showed maximum response at wavelength of 545 nm, with the optimum pH at 3. The calibration curve had a dynamic working range at 0.0 to 5.0 mM of AA with a limit of detection (LOD) of 0.13 mM AA. The membrane sensor has a long life time in the defined condition (4 o C). The developed optical chemical sensor correlated well with the standard method, HPLC for the determination of Ascorbic acid concentration in real samples.

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Section: Response Optical Sensor For Colorimetric Measurements Of Ascorbic Acidmentioning

confidence: 52%

Transparent Membrane of Polyelectrolyte Complex Doped with 2,6-Dichlorophenol-Indophenol as an Optical Sensor for Colorimetric Measurements of Ascorbic acid

Hermanto¹,

Ismillayli²,

Honiar³

et al. 2020

Orient. J. Chem

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“…Absalan et al 90 90 and Cu(II)-neocuproine reagent, 91 respectively. The sensitivity (the slopes of the calibration graphs, in particular) of the offered CN -and ascorbic acid sensors was better in the case of using water immiscible [BMIm]PF6 and [OMIm]PF6, correspondingly.…”

Section: ·4 Ionic Liquids As Modifiers Of the Surfacesmentioning

confidence: 99%

“…113 There was no evidence of leakage of the reagents from the membranes and no drifts in the signal were observed for 7 and 5 h for CN -and ascorbic acid sensors, respectively. 90,91 The application of imidazolium ILs in the SAMs on gold surfaces in SPR sensors provided the native conformation of the proteins/enzymes in the course of their chemical immobilization to be maintained that resulted in greater catalytic activity than those for other surfaces. 50 Moreover, the use of a binary monolayer of the IL-biotin and 11-mercaptoundecanol significantly reduced the nonspecific adsorption of streptavidin and, consequently, improved the selectivity of its binding by the sensor's surface.…”

Section: ·4 Ionic Liquids As Modifiers Of the Surfacesmentioning

confidence: 99%

“…90,91 The offered CN -sensor can determine 4.2 μmol dm -3 concentrations of this anion that is almost 100 times less than its lethal dose to humans: 40 -200 μmol dm -3 . 123 Moreover, unlike the disposable sensor for ascorbic acid, the CN -optode can be regenerated with HNO3.…”

Section: Application Of the Developed Optical Sensors In Chemical Anamentioning

confidence: 99%

“…(1) Fabrication of various sensing materials in the different forms (gels, hydrogels, films, and membranes) due to the unique solvent ability of ILs with respect to different matrix materials (TEOS, 70,84 cellulose, [85][86][87][88][89] EC, PMMA, and PVC [74][75][76][77][78][79][80] ), recognition elements (ligands, [77][78][79]85,86,103 indicators, 81,93,94 chromo-responsible dyes, 89 complexes, [74][75][76]80,84,87,90,91 and enzymes 70,88 ), and gaseous analytes (in particular, CO2 82 ).…”

Section: Advantages and Drawbacks Of Using Ils In Optical Sensing Tecmentioning

confidence: 99%

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Applications of Ionic Liquids for the Development of Optical Chemical Sensors and Biosensors

et al. 2017

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This paper reviews the primary literature reporting the use of ionic liquids (ILs) in optical sensing technologies. The optical chemical sensors that have been developed with the assistance of ILs are classified according to the type of resultant material. Key aspects of applying ILs in such sensors are revealed and discussed. They include using ILs as solvents for the synthesis of sensor matrix materials; additives in polymer matrices; matrix materials; modifiers of the surfaces; and multifunctional sensor components. The operational principles, design, texture, and analytical characteristics of the offered sensors for determining CO2, O2, metal ions, CN -, and various organic compounds are critically discussed. The key advantages and disadvantages of using ILs in optical sensing technologies are defined. Finally, the applicability of the described materials for chemical analysis is evaluated, and possibilities for their further modernization are outlined.

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Recent advances and applications of ionic liquids-based photonic materials

Mahato

Murakami

Das

2023

Applied Materials Today

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Construction of an Optical Sensor for the Determination of Ascorbic Acid Using Ionic Liquids as Modifier

Cited by 5 publications

References 36 publications

Transparent Membrane of Polyelectrolyte Complex Doped with 2,6-Dichlorophenol-Indophenol as an Optical Sensor for Colorimetric Measurements of Ascorbic acid

Transparent Membrane of Polyelectrolyte Complex Doped with 2,6-Dichlorophenol-Indophenol as an Optical Sensor for Colorimetric Measurements of Ascorbic acid

Applications of Ionic Liquids for the Development of Optical Chemical Sensors and Biosensors

Recent advances and applications of ionic liquids-based photonic materials

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