“…Among the XRF-based studies (Table S1), some aimed in distinguishing among the Western Mediterranean obsidian sources [40,47,68,71,[73][74][75]78,79], or focused on Monte Arci sub-sources discrimination [40,47,69,70,[72][73][74][76][77][78][81][82][83][84][85][86][87]. The number of geological samples analysed by XRF was lower or equal to 25 in some studies [68,71,73,79,81] and between 35 and 60 in the other references [47,70,72,74,77,78]. Most of the analytical methods are based on the use of absolute concentrations [40,68,[70][71][72][75][76][77][78], obtained based on the calibration of the intensities through the analysis of reference materials, i.e.…”