Ionisation growth in the gas mixtures, N2:NO, N2:He and CO2:N2:He has been studied using combined spatial and temporal measurement techniques. Observations in N2:NO mixtures confirmed that reliable information about primary ionisation processes could be obtained even in the presence of large secondary surface ionisation processes and extensive studies of the two ternary mixtures CO2:N2:He (1:1:8) and (1:2:3) and one binary N2:He (1:9) mixture have been undertaken. Primary and secondary ionisation coefficients covering the range of values 60