Coordinating activation strategy enables 1,2-alkylamidation of alkynes
Jing Ren,
Junhua Xu,
Xiangxiang Kong
et al.
Abstract:The radical 1,2-difunctional alkylamidation of alkynes has been developed with the help of a bidentate coordinating group for the synthesis of β-alkylated enamides.
The vinyl radical is a destabilized radical with a single electron in an sp2 hybridized orbital, with high reactivity and some electrophilicity. It was mentioned in seminal works published by...
The vinyl radical is a destabilized radical with a single electron in an sp2 hybridized orbital, with high reactivity and some electrophilicity. It was mentioned in seminal works published by...
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