2023
DOI: 10.3390/cryst13091300
|View full text |Cite
|
Sign up to set email alerts
|

Coordinative Unsaturation in an Antimony(III)-Complex with the 2-Salicylidenaminophenolato Ligand: Synthesis, Crystal Structure, Spectroscopic Analysis, and DFT Studies

Steven Knerr,
Uwe Böhme,
Marcus Herbig

Abstract: In this work, the synthesis and structure of an antimony complex with an aromatic, asymmetric tridentate ligand without an Sb-C bond were studied. Ethoxy(2-salicylidenaminophenolato)antimony(III) was studied with NMR, UV-Vis, and IR spectroscopy and the molecular structure was determined by single crystal X-ray diffraction. The antimony atom is formally tetracoordinate in this molecule. Coordinative unsaturation becomes visible in the solid-state structure where intermolecular Sb…O interactions supplement the … Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
0
0

Year Published

2024
2024
2024
2024

Publication Types

Select...
1

Relationship

0
1

Authors

Journals

citations
Cited by 1 publication
references
References 61 publications
0
0
0
Order By: Relevance