Copper and cadmium coordination polymers of di-3-pyridinylmethanone: Subtle anion effect on the dimensionality of Cd(II) frameworks

Chen, Xudong; Guo, Jian‐Hua; Du, Miao; Mak, Thomas C. W.

doi:10.1016/j.inoche.2005.06.001

Cited by 15 publications

(2 citation statements)

References 22 publications

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“…1.987 (10)] are significantly shorter than the Cu-O (hydroxyl) bond [av. 2.86 (10)], in which is also found in other complexes [19,[32][33][34][35].…”

Section: Syntheses Of the Complexessupporting

confidence: 54%

Solvothermal syntheses and structural characterization of a series of metal–hydroxycarboxylate coordination polymers

Liu

Wang

et al. 2008

Inorganica Chimica Acta

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“…1.987 (10)] are significantly shorter than the Cu-O (hydroxyl) bond [av. 2.86 (10)], in which is also found in other complexes [19,[32][33][34][35].…”

Section: Syntheses Of the Complexessupporting

confidence: 54%

Solvothermal syntheses and structural characterization of a series of metal–hydroxycarboxylate coordination polymers

Liu

Wang

et al. 2008

Inorganica Chimica Acta

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“…The process of the self-assembly of a supramolecular framework is based on the extension of individual molecules by noncovalent or weak covalent interactions, including Van der Waals, electrostatic and hydrophobic interactions, hydrogen bonds, as well as p-p and ion-p stacking [11][12][13][14][15][16][17][18][19][20][21]. Among these, hydrogen bonding and p-p stacking interactions have been considered to play active roles in the formation of ordered supramolecular chains, layers, and three-dimensional frameworks, the research on which is of great interest for the development of supramolecular chemistry [22][23][24][25][26][27][28][29].…”

Section: Introductionmentioning

confidence: 99%

Synthesis, crystal structure, and luminescent properties of metal complexes bearing 2,6-pyridine-diacylhydrazide ligands: supramolecular assemblies via intermolecular interactions

Qin

Chen

Liu

et al. 2011

Transition Met Chem

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Four metal complexes of N,N 0 -bis(salicyl)-2,6-pyridine-dicarbohydrazide 4 ]ÁDMFÁH 2 O (4), were synthesized and characterized by elemental analysis, IR, and single-crystal X-ray diffraction analysis. Structural studies revealed that complexes 1-3 present discrete mononuclear structures and complex 4 displays a centrosymmetric mixedvalence trinuclear structure. All four complexes are further extended into interesting two-or three-dimensional supramolecular frameworks. The luminescent properties of 2 and 3 were studied, which show emissions with maxima at 485 nm upon excitation at 396 nm for 2 and 476 nm upon excitation at 397 nm for 3, respectively.

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Adventures in the Coordination Chemistry of Di‐2‐pyridyl Ketone and Related Ligands: From High‐Spin Molecules and Single‐Molecule Magnets to Coordination Polymers, and from Structural Aesthetics to an Exciting New Reactivity Chemistry of Coordinated Ligands

et al. 2009

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The coordination chemistry of di-2-pyridyl ketone and related ligands is reviewed. An outline of the variety of such ligands is presented. References are given to methods for the synthesis of ligands that are not available on the market. The activation of the carbonyl group(s) of some of the ligands towards further reactions seems to be an emergent area of synthetic inorganic chemistry. The coordination chemistry of each ligand with metals is briefly described. Emphasis is placed on structural features and physical properties (mainly magnetic) of the resulting metal clusters and coordination polymers. The structural diversity of the complexes stems from the ability of the deprotonated diol-or hemiketal-type Organization of This Microreview and General InformationThis Microreview presents a focused overview of the coordination chemistry of ligands with the general formulae X-CO-X, X-CO-Y, X-CO-CO-X, and X-CO-X-CO-X, where X and Y are donor groups. We mainly describe the polynuclear metal complexes (clusters) and coordination polymers that have derived from the use of these ligands and the organic chemistry of their metal complexes. From the viewpoint of properties, emphasis is placed on the magnetism of the metal complexes. Much of the chemistry, both published and unpublished, that is reported comes from our group; however, detailed reference to all appropriate work by others is provided. The Microreview aims not to be comprehensive in terms of a discussion of every known cluster or coordination polymer containing a ligand derived from the above-mentioned molecules; rather, it aims to provide [ ‡] ligands to adopt a variety of bridging coordination modes depending on the number of carbonyl groups, the nature of the extra donor groups in the molecule and on the reaction conditions. Employment of a second organic or inorganic ligand in this chemistry gives an extraordinary structural flexibility in the resulting mixed-ligand systems. The initial use of 1,1Ј-carbonyldiimidazole and 1,1Ј-oxalyldiimidazole in copper(II) chemistry, which leads to unprecedented coordination polymers containing alcoholysis and/or hydrolysis "fragments" of the ligands, is also illustrated.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009) the reader with some idea of the range of chemistry that has been carried out (and indeed remains still to do) with these ligands. The article contains eight sections, including this one. The next section is introductory: the reader can find brief, general information on the two classes of compounds that are frequently mentioned in this Microreview, namely metal clusters and polymers, as well as a short discussion of the organic chemistry of metal complexes, which is currently a popular topic in inorganic chemistry. The last part of Section 2 provides a "hors d'oeuvre" of the ligands that are discussed in detail in Sections 3-7. Section 8 provides initial conclusions and perspectives for future research. Sections 2 and 3 are divided into parts for clarity. The organization of this ...

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Copper and cadmium coordination polymers of di-3-pyridinylmethanone: Subtle anion effect on the dimensionality of Cd(II) frameworks

Cited by 15 publications

References 22 publications

Solvothermal syntheses and structural characterization of a series of metal–hydroxycarboxylate coordination polymers

Solvothermal syntheses and structural characterization of a series of metal–hydroxycarboxylate coordination polymers

Synthesis, crystal structure, and luminescent properties of metal complexes bearing 2,6-pyridine-diacylhydrazide ligands: supramolecular assemblies via intermolecular interactions

Adventures in the Coordination Chemistry of Di‐2‐pyridyl Ketone and Related Ligands: From High‐Spin Molecules and Single‐Molecule Magnets to Coordination Polymers, and from Structural Aesthetics to an Exciting New Reactivity Chemistry of Coordinated Ligands

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