Abstract:A convenient Pd- and phosphine-free protocol for assembling internal alkynes from tertiary propargyl alcohols and (het)aryl halides has been developed. The proposed tandem approach includes base-promoted retro-Favorskii fragmentation followed by...
Photosensitizer-free visible light-mediated cross-coupling of aryldiazonium tetrafluoroborates and alkynyltrimethylsilanes has been achieved using a recyclable SBA-15-anchored triphenylphosphine–gold(i) complex as a catalyst.
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