Correlating High-Temperature Defect and Magnetic Structures with Anomalous Chemical Expansion in an Outstanding PrBa0.5Sr0.5Co1.5Fe0.5O6−δ Positrode
B. V. Politov,
D. A. Shishkin,
A.Yu. Suntsov
Abstract:In this study, PrBa 0.5 Sr 0.5 Co 1.5 Fe 0.5 O 6−δ (PBSCF) oxide with a layered double perovskite structure was successfully synthesized and characterized using the combination of X-ray diffraction (XRD) and energy-dispersive X-ray (EDX) methods. Oxygen content and electrical conductivity of PBSCF were measured at elevated temperatures and variable oxygen partial pressures. The corresponding experimental data were successfully analyzed using earlier proposed defect formation and transport models; the obtained … Show more
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