Methods for remote monitoring of plumes of radioactive releases are considered. The process of track ionization by electrons in the radioactive plume of the emission is considered in detail. Analysis of ion formation in the troposphere was carried out. The effect of secondary radiation on the kinetics of ions in the troposphere has been studied. Highenergy electrons appear as a result of the decay of beta-radioactive radionuclides released into the atmosphere. It is shown that the methods based on secondary radiation are the most promising. The main atmospheric reactions leading to the appearance of free electrons are considered. The influence of track ionization under the influence of radioactivity in the standard atmosphere is determined.