The most widely adopted category of the mid-range wireless power transmission (WPT) systems is based on the magnetic resonance coupling (MRC), which is appropriate for a very wide range of applications. The primary concerns of the WPT/MRC system design are the power transfer capabilities. Using the scattering parameters based on power waves, the power transfer of an asymmetric WPT/MRC system with the series-series compensation structure is studied in this paper. This approach is very convenient since the scattering parameters can provide all the relevant characteristics of the WPT/MRC system related to power propagation. To maintain the power transfer capability of the WPT/MRC system at a high level, the scattering parameter S21 is used to determine the operating frequency of the power source. Nevertheless, this condition does not coincide with the maximum possible power transfer efficiency of the system. In this regard, the WPT/MRC system is thereafter configured with a matching circuit, whereas the scattering parameter S21′ S21’is used to calculate and then adjust the matching frequency of the system. This results in the maximum available power transfer efficiency and thereby increases the overall performance of the system. Theoretical investigations are followed by numerical simulation and experimental validation.