Cover and Barrier Layers for Thin-Film Rechargeable Lithium Battery

Hayashi, Saori; Ono, Hiroaki; Matsuo, Takuji; Sato, Susumu; Sabi, Yuichi; Onodera, S.

doi:10.1149/ma2010-03/1/687

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Observation With Optical Ellipsometer1

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2011

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“…On top of the anode collector Ti, UV curable resin can be spin-coated to improve the charge/discharge cycle durability 5 . The LiCoO 2 thin additive layer drastically improved the cycle durability of the Li-free thin-film battery as shown in Fig.…”

Section: Methodsmentioning

confidence: 99%

“…The thickness deviation from theoretical value is mainly due to over-lithiation of LiCoO 2 thin film. Also, since the plating does not appear as flat surface since the sample is not prepared with UV resin cover 5 , scattering may have influenced the fit thickness to appear thinner.…”

Section: Observation With Optical Ellipsometermentioning

confidence: 99%

“…A "Li-free" Li anode structure for such system is under investigation in aim for simpler process and lower cost production 2 . Recently, LiCoO 2 thin film was introduced at the boundary between the anode current collector and the LiPON layer, leading to drastically improved charge/discharge cycling property [3][4][5] . However, the Li plating in such "Li-free" systems is not yet clearly observed nor analyzed.…”

mentioning

confidence: 99%

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