Creatininium cinnamate

Ali, Akram; Athimoolam, S.; Bahadur, S. Asath

doi:10.1107/s1600536811016916

Cited by 5 publications

(1 citation statement)

References 10 publications

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“…[10,11] Most of the creatinine compounds are centrosymmetric and comprise high optical non-linearity. [12,13] Creatinium perchlorate, [14] Creatininium hydrogen maleate, [15] Creatininium 2-chloroacetate, [16] Creatininium dihydrogen arsenate, [17] and Creatininium benzoate [18] were reported. In this present study, the authors have grown a single crystal of Creatininium hydrochloride (C 4 H 8 N 3 O + Cl − ) using a low-temperature solution method.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Characterization of Single Crystals of Creatininium Hydrochloride for Third‐Order NLO Applications

Meeraa,

Parthasarathy

2023

Cryst. Res. Technol.

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Single crystals of Creatininium hydrochloride (CTNHCl) are grown by the conventional solution growth method using Millipore water at 32 °C. X‐ray diffraction reveals that it crystallizes in a monoclinic with a space group of P21/n. Solubility studies are performed at different temperatures. Intermolecular interactions involving distinct molecular moieties are also studied by mapping the 3D Hirshfeld surface and its fingerprint plots. Using FT‐IR, spectral analysis is identified. The optical efficiency of the material is studied using UV–vis–NIR and photoluminescence studies. SEM and EDAX analysis are performed for the title compound. Thermal behavior is analyzed, and the material started to melt at 275 °C. Third‐order nonlinear properties of the material like β, n2, χ(3) values are calculated using the z‐scan technique.

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Section: Introductionmentioning

confidence: 99%

Synthesis and Characterization of Single Crystals of Creatininium Hydrochloride for Third‐Order NLO Applications

Meeraa,

Parthasarathy

2023

Cryst. Res. Technol.

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Creatininium hydrogen maleate

Ali¹,

Athimoolam²,

Bahadur

2011

Acta Cryst E

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In the title compound, C4H8N3O+·C4H3O4 −, the cations and anions are linked through N—H⋯O hydrogen bonds making a ionic pair with an R 2 2(8) ring motif. These ionic pairs are further connected through another N—H⋯O hydrogen bond, leading to an R 6 6(16) ring motif around the inversion centres of the unit cell. These approximately planar aggregates are further connected through weak van der Waals interactions in the unit cell. The anions have a characteristic intramolecular O—H⋯O hydrogen bond with a self-associated ring S(7) motif.

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Creatinium hydrogen oxalate

Ali

Athimoolam²,

Bahadur

2012

Acta Cryst E

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The crystal structure of the title compound, C4H10N3O2 +·C2HO4 −, is stabilized by N—H⋯O and O—H⋯O hydrogen bonds. The anions are connected by an O—H⋯O hydrogen bond, leading to C(5) chain extending along c axis. The cations are dimerized around the corners of the unit cell, leading to an R 2 2(14) ring motif. This leads to a cationic molecular aggregation at x = 0 or 1 and an anionic molecular aggregation at x = 1/2.

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Creatininium cinnamate

Cited by 5 publications

References 10 publications

Synthesis and Characterization of Single Crystals of Creatininium Hydrochloride for Third‐Order NLO Applications

Synthesis and Characterization of Single Crystals of Creatininium Hydrochloride for Third‐Order NLO Applications

Creatininium hydrogen maleate

Creatinium hydrogen oxalate

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