2024
DOI: 10.1021/acs.chemrev.4c00524
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Cross-Electrophile Coupling: Principles, Methods, and Applications in Synthesis

Lauren E. Ehehalt,
Omar M. Beleh,
Isabella C. Priest
et al.

Abstract: Cross-electrophile coupling (XEC), defined by us as the cross-coupling of two different σ-electrophiles that is driven by catalyst reduction, has seen rapid progression in recent years. As such, this review aims to summarize the field from its beginnings up until mid-2023 and to provide comprehensive coverage on synthetic methods and current state of mechanistic understanding. Chapters are split by type of bond formed, which include C(sp 3 )−C(sp 3 ), C(sp 2 )−C(sp 2 ), C(sp 2 )−C(sp 3 ), and C(sp 2 )−C(sp) bo… Show more

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