Cross-linkable and thermally stable aliphatic polycarbonates derived from CO2, propylene oxide and maleic anhydride

Song, Pengfei; Wang, Shuanjin; Xiao, Min; Du, F. G.; Gan, Li-qiang; Liu, Guoqing; Ye, Meng

doi:10.1007/s10965-008-9206-2

Cited by 31 publications

(21 citation statements)

References 21 publications

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“…www.chemsuschem.org nology involving a supported zinc glutarate catalyst for the copolymerization of CO 2 and propylene oxide. [80] Although fixation in polymers achieves the long-term sequestration desired in carbon management strategies proposed by IPCC special report on CO 2 capture and storage, [23] the impact on the reduction of CO 2 emissions by year 2020assuming that CO 2 -PC will constitute 30 % of world PC production (current world consumption of polycarbonates about 2.7 Mt a À1 )-will be about 0.3-0.5 Mt a À1 . Although the market share could grow faster and the overall PC market could increase, the tonnages involved are not expect to go over the Mt a À1 mark for sequestration of CO 2 .…”

Section: Alternating Polyolefin Carbonate Polymersmentioning

confidence: 99%

Carbon Dioxide Recycling: Emerging Large‐Scale Technologies with Industrial Potential

et al. 2011

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This Review introduces this special issue of ChemSusChem dedicated to CO(2) recycling. Its aim is to offer an up-to-date overview of CO(2) chemical utilization (inorganic mineralization, organic carboxylation, reduction reactions, and biochemical conversion), as a continuation and extension of earlier books and reviews on this topic, but with a specific focus on large-volume routes and projects/pilot plants that are currently emerging at (pre-)industrial level. The Review also highlights how some of these routes will offer a valuable opportunity to introduce renewable energy into the existing energy and chemical infrastructure (i.e., "drop-in" renewable energy) by synthesis of chemicals from CO(2) that are easy to transport and store. CO(2) conversion therefore has the potential to become a key pillar of the sustainable and resource-efficient production of chemicals and energy from renewables.

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Section: Alternating Polyolefin Carbonate Polymersmentioning

confidence: 99%

Carbon Dioxide Recycling: Emerging Large‐Scale Technologies with Industrial Potential

et al. 2011

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“…The most important work is to enhance the thermal and mechanical properties of PPC, and introducing a third monomer into the copolymerization of CO 2 and PO is considered a profitable means [12][13][14][15][16]. Terpolymerization of CO 2 , propylene oxide (PO) with cyclohexene oxide (CHO), [(2-naphthyloxy)methyl] oxirane (NMO), N-(2,3-epoxylpropyl) carbazole or maleic anhydride (MA) has been reported [17][18][19][20][21][22]. The resultant products show improved thermal and mechanical properties as compared with PPC.…”

Section: Introductionmentioning

confidence: 99%

Novel ternary block copolymerization of carbon dioxide with cyclohexene oxide and propylene oxide using zinc complex catalyst

et al. 2012

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Block copolymers of poly (propylene carbonatecyclohexyl carbonate) (PPC-PCHC) were successfully synthesized by a one-pot method with the zinc complex catalyst (Zn2G). The IR and 1 H-NMR and 13 C-NMR spectra verified the introducing of PCHC segments in the copolymers. The GPC curves of the copolymers appeared only one peak and the DSC results showed three glass transition temperatures at 40°C, 66°C and 115°C, indicating the three-block copolymer structure. TGA tests revealed that the thermal decomposition temperature of the synthesized block copolymers increased up to about 300°C. The mechanical properties proved to be also enhanced greatly as evidenced by static and dynamic mechanical tests. The thermal and mechanical properties of the resultant block copolymers lay between those of PPC and PCHC, demonstrating the desired properties of a polymer can be achieved via block copolymerization.

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“…The PPC has been chosen for its excellent properties such as low cost, high dielectric strength and high surface resistivity; and it is considered as one of the important polymers for biomedical and engineering application . It also exhibits high transparency and superior mechanical strength (Song et al, 2009). These attractive properties make the PPC a good substrate for a variety of microelectronic applications.…”

Section: Characteristics Of Zno Thin Films Deposited On Ppc Plasticmentioning

confidence: 99%

ZnO Metal-Semiconductor-Metal UV Photodetectors on PPC Plastic with Various Metal Contacts

Jandow¹,

Hassan²,

Yam³

et al. 2012

Photodetectors

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Cross-linkable and thermally stable aliphatic polycarbonates derived from CO2, propylene oxide and maleic anhydride

Cited by 31 publications

References 21 publications

Carbon Dioxide Recycling: Emerging Large‐Scale Technologies with Industrial Potential

Carbon Dioxide Recycling: Emerging Large‐Scale Technologies with Industrial Potential

Novel ternary block copolymerization of carbon dioxide with cyclohexene oxide and propylene oxide using zinc complex catalyst

ZnO Metal-Semiconductor-Metal UV Photodetectors on PPC Plastic with Various Metal Contacts

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