Crystal Structure and Hirshfeld Surface Analysis of (E)-5-Phenyl-3-((4-(Trifluoromethyl)benzylidene)amino)thiazolidin-2-Iminium Bromide

Abstract

In the cation of the title salt, the central thiazolidine ring adopts an envelope conformation. In the crystal N-H ••• Br hydrogen bonds link the components into a bi-dimensional network with the cations and anions stacked parallel to plane (101). The molecular structure shows several positional disorders over-CF 3 and thiazolidine fragments and these were modeled. The weak intermolecular interactions in the crystal structure are mainly const Hirshfeld surface analysis were used to verify the contributions of the different intermolecular interactions.

Crystal structure and Hirshfeld surface analysis of (E)-3-(benzylideneamino)-5-phenylthiazolidin-2-iminium bromide

“…Nowadays, N-ligands are key players in a wide diversity of fields, namely in coordination, metal-organic, pharmaceutical and medicinal chemistry, biologically active compounds, catalysis, non-covalent interactions and supramolecular assemblies (Maharramov et al, 2011(Maharramov et al, , 2018Mahmudov et al, 2013Mahmudov et al, , 2014Mahmudov et al, , 2017aMahmudov et al, ,b, 2019Mamedov et al, 2015). In our previous studies we have reported on the molecular structural properties of a series of 5-phenylthiazolidin-2-imine derivatives (Akkurt et al, 2018a,b;Duruskari et al, 2019a,b;Khalilov et al, 2019;Maharramov et al, 2019). Following further study in this field, herein we report the crystal structure and Hirshfeld surface analysis of the title compound, (E)-3-(benzylideneamino)-5phenylthiazolidin-2-iminium bromide.…”

Crystal structure and Hirshfeld surface analysis of 5,7-diphenyl-1,2,3,5,6,7-hexahydroimidazo[1,2-a]pyridine-6,6,8-tricarbonitrile methanol monosolvate

“…Having a great methodological diversity, C-C and C-X (where X is a heteroatom) bond-forming reactions lie at the heart of synthetic organic chemistry (Khalilov et al, 2018a,b;Maharramov et al, 2019;Cheng & Mankad, 2020). They allow the construction of complex molecular structures and the introduction of various substituents.…”

Crystal structure and Hirshfeld surface analysis of ethyl 6′-amino-2′-(chloromethyl)-5′-cyano-2-oxo-1,2-dihydrospiro[indoline-3,4′-pyran]-3′-carboxylate

“…(Yadigarov et al, 2009;Khalilov et al, 2018a,b;Zubkov et al, 2018). These methods have found widespread application in the design of diverse heterocyclic ring systems, as well as spiro-heterocyclic compounds (Gurbanov et al, 2018;Maharramov et al, 2019;Mahmoudi et al, 2019;Mamedov et al, 2019;Yin et al, 2020). The spirooxindole moiety is a key bioactive fragment of various natural products (Fig.…”