Crystal structure and Hirshfeld surface analysis of 2-azido-N-(4-fluorophenyl)acetamide

Abstract

The asymmetric unit of the title compound, C8H7FN4O, consists of two independent molecules differing in the orientation of the azido group. Each molecule forms N—H...O hydrogen-bonded chains along along the c-axis direction with its symmetry-related counterparts and the chains are connected by C—F...π(ring), C=O...π(ring) and slipped π-stacking interactions. A Hirshfeld surface analysis of these interactions was performed.