Crystal structure of an unknown tetrahydrofuran solvate of tetrakis(μ₃-cyanato-κ³N:N:N)tetrakis[(triphenylphosphane-κP)silver(I)]

Abstract

In the title compound a distorted Ag4N4-heterocubane core is set up by AgI cations and N atoms of cyanate anions. The core is decorated by four tri­phenyl­phosphine ligands bonded to the AgI cations. Ag⋯Ag distances as short as 3.133 (9) Å suggest the presence of argentophilic (d 10⋯d 10) inter­actions.