Cu (II) decorated thiol-functionalized MOF as an efficient transfer medium of charge carriers promoting photocatalytic hydrogen evolution

Mao, Siman; Shi, Jian‐Wen; Sun, Guotai; Zhang, Yijun; Ji, Xin; Lv, Yixuan; Wang, Baorui; Xu, Yurong; Cheng, Yonghong

doi:10.1016/j.cej.2020.126533

Cited by 100 publications

(38 citation statements)

References 65 publications

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“…Moreover, the Mott–Schottky plots of PANI and NENP-1 were conducted to confirm the band positions versus saturated calomel electrode (SCE). 45 The flat band ( V fb ) potential measured for PANI and NENP-1 is −2.10 and −1.60 eV in Fig. S4,† concerning the SCE, respectively.…”

Section: Resultsmentioning

confidence: 99%

An investigation on PANI/NENP-1 composite as a novel photocatalyst for photocatalytic dye wastewater degradation and photocatalytic hydrogen evolution

et al. 2022

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Section: Resultsmentioning

confidence: 99%

An investigation on PANI/NENP-1 composite as a novel photocatalyst for photocatalytic dye wastewater degradation and photocatalytic hydrogen evolution

et al. 2022

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“…[145][146][147][148] A similar strategy is used to prepare composites containing metal sulfide and MOFs. [149][150][151][152][153][154][155][156][157][158][159][160][161][162][163] Interestingly, growing MOFs or COFs on the surface of pristine MOFs has recently been demonstrated to be a novel strategy for constructing effective photocatalysts. [164][165][166][167] These works indicate that the in situ growth of semiconductors on/within MOFs opens a new and facile avenue, which enables MOFs to be promising candidates for large-scale application of photocatalysis.…”

Section: Psm Of Surface and Interiormentioning

confidence: 99%

“…[142,193] In these systems, the created intimate interfacial interactions between the inorganic semiconductor and host MOFs effectively promote the separation/migration of photogenerated electron and hole pairs, thus achieving higher photocatalytic performance than pure MOF. [123,139,140,142,151,152,157,160,161,[194][195][196] For example, a series of pÀn heterojunction photocatalysts, BN-X, was obtained through integrating BiOI into the pores of NU-1000 (Figure 6a). [142] The modified composites exhibited improved separation efficiency of photogenerated electrons and holes due to the internal electric field of BN-X, verified by transient photocurrent response and electrochemical impedance spectroscopy (EIS) (Figure 6b,c).…”

Section: Water Splittingmentioning

confidence: 99%

Postsynthetic Modification of Metal−Organic Frameworks for Photocatalytic Applications

Lin

Wang

et al. 2022

Small Structures

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Metal−organic frameworks (MOFs) are a new class of porous, crystalline materials with promising applications in the fields of energy and environment. Postsynthetic modification (PSM) approaches are shown to be powerful techniques to introduce new functionalities to parent frameworks. PSM methods to functionalize MOFs can be divided into four main categories based on their unique structures: covalent modification, coordinative transformation, encapsulation, and hybridization with other compounds. These approaches are proven to be an important tool for increasing structural stability and introducing desired properties, which expand the applications of MOFs. This review focuses on the current advancements of four PSM methods to construct functionalized MOFs for photocatalytic applications in water splitting, CO2 reduction, organic transformation, and degradation of water pollutants. The challenge and perspectives on PSM of MOFs for photocatalysis are also discussed.

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“…[ 28 ] In another example, a new Zr‐based MOF composite photocatalyst is prepared by combining UiO‐66 with organic functional groups for PC water splitting. [ 29 ] The SH groups are applied to modify the BDC linker to form the UiOS, as indicated in Figure 2d. Then, Cu ions are anchored onto the UiOS framework because of the coordination of CuS bonds.…”

Section: Mof‐based Materials Applied In Pcmentioning

confidence: 99%

Metal–Organic Framework‐Based Materials for Solar Water Splitting

Wang

2021

Small Science

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Solar‐driven water splitting is a promising way to produce renewable hydrogen. The design of efficient semiconductor photocatalysts plays a vital role in this process. The recent dynamic development of metal–organic framework (MOF) materials provides a good opportunity to design efficient composite photocatalysts toward solar water splitting. Herein, a critical review of the design and development of MOF/semiconductor composite photocatalysts for solar‐driven water splitting is presented. The designing strategies of MOF‐based composite photocatalysts, including the use of organic ligands, quantum dots and carbon‐based materials to form heterostructures, and the combination of MOF layers with semiconductors to fabricate thin‐film photoelectrodes for photoelectrochemical water splitting, are introduced. The remaining challenges and future perspectives of the MOF‐based composites with the hope of achieving improved solar water splitting are also discussed.

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Cu (II) decorated thiol-functionalized MOF as an efficient transfer medium of charge carriers promoting photocatalytic hydrogen evolution

Cited by 100 publications

References 65 publications

An investigation on PANI/NENP-1 composite as a novel photocatalyst for photocatalytic dye wastewater degradation and photocatalytic hydrogen evolution

An investigation on PANI/NENP-1 composite as a novel photocatalyst for photocatalytic dye wastewater degradation and photocatalytic hydrogen evolution

Postsynthetic Modification of Metal−Organic Frameworks for Photocatalytic Applications

Metal–Organic Framework‐Based Materials for Solar Water Splitting

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