CuInS2/Poly(triarylamine) (PTAA) binary composite as an efficient hole transporter for carbon electrode-based perovskite solar cells

Kassem, Hassan; Salehi, Alireza; Kahrizi, Mojtaba; Jamali, Ziba

doi:10.1016/j.materresbull.2023.112557

Cited by 4 publications

(3 citation statements)

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“…The shaded areas are meant as guides for the eye to highlight the inverse ΔE V -V OC relationship and the direct ΔE V -FF relationship. [29,110,158,182,184,[225][226][227] low-temperature C-PSCs has been possible, leading to some of the highest efficiencies reported for such devices. [158] Other organic HSLs that are not sensitive to carbon paste solvent and binder compatibility, such as P3HT, phthalocyaninebased compounds like CuPc and ZnPc, and inorganic materials like NiO x , have also shown promising results in the literature.…”

Section: Materials Development For Hsls In C-pscsmentioning

confidence: 99%

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Carbon Electrodes for Perovskite Photovoltaics: Interfacial Properties, Meta‐analysis, and Prospects

Zouhair,

Clegg,

Valitova

et al. 2024

Solar RRL

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Carbon electrodes have gained significant attention as a cost‐effective, sustainable, stable, and scalable replacement for metal electrodes in perovskite solar cells (PSCs). However, traditional carbon‐electrode‐based PSCs (C‐PSCs) lack a hole‐selective layer (HSL) due to their incompatibility with the most effective organic HSLs employed in the PSC literature. In turn, the absence of an HSL has been identified as one of the main factors hindering the performance of C‐PSCs. Consequently, numerous studies have recognized the pivotal significance of the region between the perovskite absorber and the carbon electrode in C‐PSCs, proposing various interfacial engineering strategies to improve the performance of these solar cells. Given the rapid evolution of this field, an up‐to‐date and comprehensive review of C‐PSCs is in order. Key areas of focus of this review include the shift from high‐temperature to low‐temperature carbon electrodes, strategies to improve energetic alignment at the interface, novel approaches such as hole‐selective bilayers, and alternative carbon deposition methods to reduce solvent damage. Additionally, this review presents a comprehensive meta‐analysis—the first of its kind in the C‐PSC literature—to assess how various interfacial modifications impact critical C‐PSC performance metrics, offering valuable insights for future advancements in the field.This article is protected by copyright. All rights reserved.

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Section: Materials Development For Hsls In C-pscsmentioning

confidence: 99%

“…The shaded areas are meant as guides for the eye to highlight the inverse Δ E V – V OC relationship and the direct Δ E V –FF relationship. [ 29,110,158,182,184,225–227 ]…”

Section: Meta‐analysismentioning

confidence: 99%

Carbon Electrodes for Perovskite Photovoltaics: Interfacial Properties, Meta‐analysis, and Prospects

Zouhair,

Clegg,

Valitova

et al. 2024

Solar RRL

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“…Compared to other organic hole-transport material (HTMs), Spiro-OMeTAD is used in high concentrations (>70 mg ml À1 according to different researchers), [27][28][29] which is about one-seventh that of other organic HTMs. [30][31][32][33][34] Despite the relatively comparable costs of the batches of each compound, the Spiro-based PSC devices are considered more expensive according to cost-per-unit scales. [35] Various classes of materials have been developed and used as HTMs for PSCs, including small molecules, π-conjugated polymers, organometallic compounds, and metal oxides.…”

Section: Introductionmentioning

confidence: 99%

Recent Advances in Poly(3‐hexylthiophene) and Its Applications in Perovskite Solar Cells

Kassem,

Salehi,

Kahrizi

2024

Energy Tech

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2,2',7,7'‐Tetrakis(N,N‐di‐p‐methoxyphenylamine)‐9,9'‐spirobifluorene (Spiro‐OMeTAD) is considered the backbone of high performance in perovskite solar cells (PSCs) with the highest recorded power conversion efficiency near 26%. Devices with Spiro‐OMeTAD as a hole‐transport material (HTM) inherit very low stability due to the use of ionic‐based and unstable hygroscopic dopants to boost their hole mobility, hindering their stability. Poly(3‐hexylthiophene) (P3HT) is considered one of the promising HTM candidates, due to its formidable physical and electronic properties including higher hole mobility and thermal and moisture‐resisting nature. Despite these advantages, pristine P3HT‐based PSCs suffer low photovoltaic performances owing to unmatched perovskite/hole‐transport layer (HTL) interface and low mobility compared to doped HTMs. Today, studies are focusing on how to manage the interface between perovskite and P3HT and improve its hole mobility to achieve significant performance records in n–i–p PSCs. Herein, the advances of P3HT HTL are reviewed and light is shed on its different related approaches. Doping strategies and structural and molecular modifications to boost the hole mobility are reviewed. Interface engineering approaches to enhance the contact between perovskite and P3HT are discussed in detail. Moreover, incorporation in future PSC applications is investigated. Finally, a summary and a short outlook are provided.

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Enhanced the efficiency of carbon based perovskite solar cells via g-C3N4 as functional additives

Yang,

Zhao,

Zhao

et al. 2025

Journal of Photochemistry and Photobiology A: Chemistry

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CuInS2/Poly(triarylamine) (PTAA) binary composite as an efficient hole transporter for carbon electrode-based perovskite solar cells

Cited by 4 publications

References 84 publications

Carbon Electrodes for Perovskite Photovoltaics: Interfacial Properties, Meta‐analysis, and Prospects

Carbon Electrodes for Perovskite Photovoltaics: Interfacial Properties, Meta‐analysis, and Prospects

Recent Advances in Poly(3‐hexylthiophene) and Its Applications in Perovskite Solar Cells

Enhanced the efficiency of carbon based perovskite solar cells via g-C3N4 as functional additives

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