Curbed of molybdenum oxido-diperoxido complex on ionic liquid body of mesoporous Bipy-PMO-IL as a promising catalyst for selective sulfide oxidation

Moaser, Azra Ghiasi; Ahadi, Arefeh; Rouhani, Shamila; Mamba, Bhekie B.; Msagati, Titus A.M.; Rostamnia, Sadegh; Kavetskyy, Taras; Dugheri, Stefano; Khaksar, Samad; Hasanzadeh, Amir; Shokouhimehr, Mohammadreza

doi:10.1016/j.molliq.2020.113388

Cited by 25 publications

(9 citation statements)

References 60 publications

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“…Moreover, the heterogenous catalyst could be easily recovered and reused for ten cycles without any loss of catalytic activity (Supplementary Scheme S13). Moaser et al prepared a new heterogenous catalyst by immobilization of the molybdenum (VI)-based oxido-peroxido complex on periodic mesoporous organosilica-supported bipyridinium ionic liquid MoO(O 2 ) 2 @Bipy-PMO-IL and studied its catalytic performance in the selective oxidation of sulfides to sulfoxides with H 2 O 2 in water (Moaser et al, 2020). A number of aryl sulfides could be efficiently converted into the corresponding sulfoxides in good to high yields (75-91%) within a short reaction time of 30 min.…”

Section: Frontiers Inmentioning

confidence: 99%

Recent Advances in Catalytic Oxidation of Organic Sulfides: Applications of Metal–Ionic Liquid Catalytic Systems

Liu

Tan

et al. 2022

Front. Chem.

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Catalytic oxidation of organic sulfides is of considerable significance in industrial chemistry and fuel industry. Therefore, numerous methods have been developed for the oxidation. Metal-containing ionic liquid-based catalysts can catalyze the selective oxidation reactions and are highly used in chemical processes, which have also been used as effective solvents, reaction media, extractants, and catalysts for the oxidation of organic sulfides including oxidative desulfurization of fuel oil. Recently, much attention is being drawn to the preparation of heterogenous catalysts based on the immobilization of metal- or nonmetal-containing ILs on diverse solid supports, which can be easily separated after the completion reaction and recycled. Therefore, there is still an increasing interest in developing new and efficient catalytic procedures for the oxidation of organic sulfides. In this review, we have outlined the recent advances in catalytic oxidation of organic sulfides including oxidative desulfurization of fuel oil. The versatilities and adaptabilities of metal–ionic liquid catalytic systems in the selective oxidation of sulfides are considered a powerful research field in these transformations.

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Section: Frontiers Inmentioning

confidence: 99%

Recent Advances in Catalytic Oxidation of Organic Sulfides: Applications of Metal–Ionic Liquid Catalytic Systems

Liu

Tan

et al. 2022

Front. Chem.

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“…The MoO(O 2 ) 2 @ Bipy-PMO-IL catalyst was reused for five consecutive runs without significant loss; however, the MoO(O 2 ) 2 @SBA-15 (without IL) significantly decreases its activity after the second run. The performance of the hybrid nanocomposite for the selective oxidation reaction of sulfides to sulfoxides under optimized conditions is summarized in Table 14 below (Moaser et al 2020).…”

Section: Oxidation Reactionmentioning

confidence: 99%

Recent developments of supported and magnetic nanocatalysts for organic transformations: an up-to-date review

Gebre

2021

Appl Nanosci

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Designing and building an ideal catalyst for organic reactions is needed to increase the efficiency, reaction conditions, and to reduce its environmental impacts. The growth of nanotechnology is realized in the production of various nano-level catalysts for different applications. The as-synthesized nanocatalysts are easily manipulated to a desired shape and size with a high surface area to volume ratio, which is their critical property of the interaction of the nanomaterials with the substrates. These days, a vast array of catalysts (nanocatalysts) such as metals, metal oxides, magnetic, and alloyed/mixed nanocatalysts are applied in organic reactions to synthesize important chemicals in industries and pharmaceutical sectors with a high yield, selectivity, and reusability via reduction/hydrogenation, oxidation, condensation, C-C coupling, cyclization, and more. Consequently, this present review highlights the application of various nanocatalysts in organic reactions by combining certain proposed reaction mechanisms that have shown the impact of nanoparticles on the reactions. The factors influencing nanocatalyst performances are also discussed. Finally, the conclusion and future prospects are conveyed.

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“…Our groups succeeded in engineering periodic mesoporous organosilicas (PMOs) 31–37 and 1D organosilica nanotube linkages with organic ethane and phenylene groups. 38 To further develop the application of organosilica nanotubes, we reported the enhanced durability of Ir-BPy-NT for water oxidation, 39 PCN-SNT and PCN-BSNT as efficient photocatalysts for H 2 generation 40 and metal-free amino-incorporated organosilica nanotubes for the cycloaddition of CO 2 to epoxides.…”

Section: Introductionmentioning

confidence: 99%

Single-pot tandem oxidative/C–H modification amidation process using ultrasmall Pd_NP-encapsulated porous organosilica nanotubes

et al. 2022

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Curbed of molybdenum oxido-diperoxido complex on ionic liquid body of mesoporous Bipy-PMO-IL as a promising catalyst for selective sulfide oxidation

Cited by 25 publications

References 60 publications

Recent Advances in Catalytic Oxidation of Organic Sulfides: Applications of Metal–Ionic Liquid Catalytic Systems

Recent Advances in Catalytic Oxidation of Organic Sulfides: Applications of Metal–Ionic Liquid Catalytic Systems

Recent developments of supported and magnetic nanocatalysts for organic transformations: an up-to-date review

Single-pot tandem oxidative/C–H modification amidation process using ultrasmall Pd_NP-encapsulated porous organosilica nanotubes

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Curbed of molybdenum oxido-diperoxido complex on ionic liquid body of mesoporous Bipy-PMO-IL as a promising catalyst for selective sulfide oxidation

Cited by 25 publications

References 60 publications

Recent Advances in Catalytic Oxidation of Organic Sulfides: Applications of Metal–Ionic Liquid Catalytic Systems

Recent Advances in Catalytic Oxidation of Organic Sulfides: Applications of Metal–Ionic Liquid Catalytic Systems

Recent developments of supported and magnetic nanocatalysts for organic transformations: an up-to-date review

Single-pot tandem oxidative/C–H modification amidation process using ultrasmall PdNP-encapsulated porous organosilica nanotubes

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Product

Resources

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Single-pot tandem oxidative/C–H modification amidation process using ultrasmall Pd_NP-encapsulated porous organosilica nanotubes