Curcumin-Melamine For Solid-Phase Microextraction of Volatile Organic Compounds from Aqueous Samples

Abstract

The hybrid coating of curcumin and melamine was prepared by a simple electrochemical method. Some physical and chemical properties of the fiber were studied by several methods such as FT-IR, scanning electron microscopy and X-ray fluorescence spectroscopy. The fiber was stable at the inlet of a gas chromatograph at temperatures up to 280°C. The fiber has been used for the extraction of ethylbenzene, toluene and xylenes (ETX). Some parameters of headspace solid-phase microextraction, including extraction time, temperature and salt amount, were optimized. Under the optimized situation, the detection limits were 0.15–0.21 μg L −1 and the linear ranges were within the range of 0.5–1,000 μg L−1 (r2 ≥ 0.99). The intra-day and inter-day relative standard deviations were 10.2–13.7 and 13.0–15.6%, respectively, at a concentration level of 10 μg L−1 from each compound by applying a single fiber. The method was used to successfully analyze wastewater and pool water samples.