In order to further understand the employment forms, employment dynamics, and employment competitiveness of college students, this paper puts forward an employment quality evaluation model based on fuzzy comprehensive evaluation and immersive virtual realization technology in combination with the employment needs and environment of college students. Through horizontal and vertical comparison, field research, and employment quality evaluation model, this paper deeply understands the employment level of college students. From the perspective of the evaluation results of the employment-related work of the 2020 college students, the excellent employment rate has reached 86.25%. From the perspective of the employment quality trend of graduates, the graduate employment quality score is 77.08, and the undergraduate and junior college students’ scores are 74.97 and 77.66, respectively. From the perspective of the excellent employment rate, the employment quality evaluation model proposed in this paper is helpful for the employment of college students.