1999
DOI: 10.1016/s0022-328x(98)01089-4
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Cyano-bridged Fe–CN–Pt–NC–Fe chain complexes: structural and spectroscopic characterization of four isomers of [{η5-(1-phenylborole)Fe(CO)2(μ-CN)}2Pt(PEt3)2]

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Cited by 14 publications
(5 citation statements)
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“…The solid-state structures of complexes 16 – 20 (Figures – and Table ) correspond to expectations for this class of compounds. The larger NPtN valence angle in 20 is undoubtedly a result of repulsion between the bulky permethylated carborane cages.…”
Section: Discussionsupporting
confidence: 60%
“…The solid-state structures of complexes 16 – 20 (Figures – and Table ) correspond to expectations for this class of compounds. The larger NPtN valence angle in 20 is undoubtedly a result of repulsion between the bulky permethylated carborane cages.…”
Section: Discussionsupporting
confidence: 60%
“…in nitrosyls) by the oxygen instead of the nitrogen [65, 66]. It might be speculated that in the case of hydrogenase, an Fe–N–C linkage could be realised [67, 68] upon increasing the irradiation wavelength and decreasing the temperature ( T  ≤ 40 K). This would result in the loss of the hydrogen bond(s) to the amino acid residues and the concomitant shift of the CN − vibrations towards lower frequencies [48], as observed in our experiments.…”
Section: Discussionmentioning
confidence: 99%
“…The intriguing similarities and differences between clusters 3 and 4 led us to extend our studies to the borole-containing carbonylmetalates, [HFe(η 5 -C 4 H 4 BPh)(CO) 2 ] - 5,6 and [Fe(η 5 -C 4 H 4 BPh)(CO) 2 CN] - , and then to the 2-boratanaphthalene derivatives 5a and b …”
Section: Introductionmentioning
confidence: 92%