Cycloalkane C₁₀H₁₈ Formation During Skeleton Isomerization of endo‐1,7,7‐Trimethyl‐2‐chloro‐bicyclo[2,2,1]heptane by AlCl₃.

Abstract

Cycloalkane C 10 H 18 Formation During Skeleton Isomerization of endo-1,7,7-Trimethyl-2-chloro-bicyclo[2,2,1]heptane by AlCl 3 . -The reaction of title chlorobicycloheptane (I) with AlCl3 (trichloroethylene, 20°C) proceeds with skeletal rearrangement to furnish a mixture of isomeric cycloalkanes with the molecular formula C10H18, C11H20, C20H28 or higher. The C10H18 isomers are identified as compounds (II) -(V). -(VISHNYAKOVA, E. V.; UTSAL', V. A.; VATLINA, L. P.; PONOMAREV, D. A.; Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 46 (2003) 8, 148-149; St. Peterburgskaya lesotekh. akad., St. Petersburg, Russia; Russ.) -Mischke 28-092