Cyclodextrins in Polymer Synthesis: Synthesis and Influence of Methylatedβ-Cyclodextrin on the Radical Polymerization Behavior of 1,1-Disubstituted 2-Vinylcyclopropane in Aqueous Medium

Influence of cyclodextrin on the solubility of a classically prepared 2-vinylcyclopropane macromonomer in aqueous solution

“…1-Ethoxycarbonyl-2-vinylcyclopropane-1-carboxylic acid ( 4 ) was synthesized following a procedure described in [ 32 ]. Diethyl 2-vinyl-1,1-cyclopropanedicarboxylate could be obtained according to [ 33 ] from sodium ethoxide, diethyl malonate and trans -1,4-dichloro-2-butene in ethanol ( Scheme 2 ).…”

“…Ethoxycarbonyl-2-vinylcyclopropane-1-carboxylic acid ( 4 ) was synthesized following a procedure described in [ 32 ]. A solution of 3 (2 g) and 4 (0.5 g, 2.7 mmol) in 50 mL of anhydrous dichlormethane in a one-necked flask equipped with a calcium chloride drying tube was cooled to 0–5 °C.…”

Semicontinuous Emulsion Polymerization of Butyl Methacrylate and 1, 3-Butadiene in the Presence of Cyclodextrins and Cytocompatibility of Dicarboxylic Acid Telechelic Oligo(butyl Methacrylate)s Derived from Ozonolysis of the Latexes

“…Several examples of polymerizations in water of hydrophobic monomers have been reported. Thus, Ritter et al formed CD‐monomer complexes and then polymerized these using radical polymerizations 10–19. These polymerizations used the unique solubilizing power of CDs so that it was possible to produce aqueous solutions of the CD‐monomer complexes formed from monomers that are otherwise water insoluble.…”

Novel Polymerization of Myrcene in Aqueous Media via Cyclodextrin-Complexes

“…Our group, for these reasons is focused on the use of cyclodextrin (CD) in polymer chemistry. Meanwhile CD's have received a great deal of industrial attention [15][16][17][18][19][20][21][22][23][24][25][26][27][28][29].…”