Deconvolution of 29Si magic-angle spinning nuclear magnetic resonance spectra of silicate glasses revisited — some critical comments

Mahler, Joachim; Sebald, Angelika

doi:10.1016/0926-2040(95)00027-n

Cited by 63 publications

(56 citation statements)

References 20 publications

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“…Both these factors can be probed by solid-state NMR spectroscopy, not only qualitatively, but, more importantly, quantitatively and with the high degree of precision. Thus based on the measurements done in well-characterized crystalline SiO 2 polymorphs an accurate empirical correlation exists between the values of 29 Si NMR isotropic chemical shift and the Si-O-Si bond angles [51][52][53][54][55]. Using this correlation it was determined that in typical silicate glasses the Si-O-Si angle changes within a 142 to 151 degree range, while in silica glasses commonly used for manufacturing window panes this angle varies from 140 to 162 degree [56].…”

Section: Bulk Na 2 O-sio 2 Glassmentioning

confidence: 96%

Multinuclear NMR study of silica fiberglass modified with zirconia

Lapina

Khabibulin

Terskikh

2011

Solid State Nuclear Magnetic Resonance

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Section: Bulk Na 2 O-sio 2 Glassmentioning

confidence: 96%

Multinuclear NMR study of silica fiberglass modified with zirconia

Lapina

Khabibulin

Terskikh

2011

Solid State Nuclear Magnetic Resonance

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“…The chemical shift distribution is usually modeled by a Gaussian distribution, whose average value δ iso (henceforth denoted "δ iso " for simplicity) and the FWHM, although this assumption has been questioned [101].…”

Section: Distributions Of Chemical Shift and Quadrupolar Parameters Imentioning

confidence: 99%

27Al NMR Studies of Aluminosilicate Glasses

Edén

2015

Annual Reports on NMR Spectroscopy

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“…from 29 Si NMR spectra of Ref . (solid curve), from Ref . (dashed curve) and from neutron diffraction data (dashed‐dotted curve), (Ref …”

Section: The Current State Of the Art: New Insight Into Medium‐range mentioning

confidence: 99%

Spying with spins on messy materials: 60 Years of glass structure elucidation byNMRspectroscopy

Eckert

2018

Int J of Appl Glass Sci

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Glasses remain a focus of attraction to fundamental researchers and materials engineers alike. The desire of controlling physical property combinations by compositional design inspires the search for fundamental structural concepts describing the short‐ and medium‐range order of the glassy state. From its early beginnings more than 60 years ago, solid‐state nuclear magnetic resonance (NMR) spectroscopy has been making significant contributions toward this objective. Being element‐selective, inherently quantitative as well as selective to the local environment, NMR in many ways presents an ideal experimental tool of structural investigation of glasses. Over the years, substantial NMR methods development, along with advances in the theoretical interpretation of NMR parameters, have significantly enhanced our fundamental knowledge of medium‐range order and of composition‐structure‐function relationships. As we are approaching the 60th anniversary of the publication of the first article dealing with this topic (A.H. Silver and P.J. Bray, The Journal of Chemical Physics 1958, 29, 984), it is time to look back at the amazing scientific trajectory this field of investigation has taken, from the early beginnings to the present state of the art. As such, this overview does not strive to be comprehensive, but adopts a personal perspective, highlighting what in the view of the author have been influential developments and important insights obtained during the various phases of scientific inquiry in this research field.

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Deconvolution of 29Si magic-angle spinning nuclear magnetic resonance spectra of silicate glasses revisited — some critical comments

Cited by 63 publications

References 20 publications

Multinuclear NMR study of silica fiberglass modified with zirconia

Multinuclear NMR study of silica fiberglass modified with zirconia

27Al NMR Studies of Aluminosilicate Glasses

Spying with spins on messy materials: 60 Years of glass structure elucidation byNMRspectroscopy

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