Deep eutectic solvents composed of bio-phenol-derived superbase ionic liquids and ethylene glycol for CO<sub>2</sub> capture

Wang, Ze; Wang, Zonghua; Huang, Xin; Yang, Dezhong; Wu, Congyi; Chen, Jie

doi:10.1039/d1cc06856c

Cited by 39 publications

(25 citation statements)

References 37 publications

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“…In this case, the CO 2 solubility reached up to 5 mol/kg. Some DESs have been made by mixing ILs ethylene glycol and 4-methylimidazole ( Fu et al, 2021b ; Wang et al, 2021c ; Lee et al, 2021 ; Wang et al, 2022a ).…”

Section: Literature Survey Data Collection Properties Perdition and I...mentioning

confidence: 99%

Reviewing and screening ionic liquids and deep eutectic solvents for effective CO2 capture

Foorginezhad

2022

Front. Chem.

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CO2 capture is essential for both mitigating CO2 emissions and purifying/conditioning gases for fuel and chemical production. To further improve the process performance with low environmental impacts, different strategies have been proposed, where developing liquid green absorbent for capturing CO2 is one of the effective options. Ionic liquids (IL)/deep eutectic solvents (DES) have recently emerged as green absorbents with unique properties, especially DESs also benefit from facile synthesis, low toxicity, and high biodegradability. To promote their development, this work summarized the recent research progress on ILs/DESs developed for CO2 capture from the aspects of those physical- and chemical-based, and COSMO-RS was combined to predict the properties that are unavailable from published articles in order to evaluate their performance based on the key properties for different IL/DES-based technologies. Finally, top 10 ILs/DESs were listed based on the corresponding criteria. The shared information will provide insight into screening and further developing IL/DES-based technologies for CO2 capture.

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Section: Literature Survey Data Collection Properties Perdition and I...mentioning

confidence: 99%

Reviewing and screening ionic liquids and deep eutectic solvents for effective CO2 capture

Foorginezhad

2022

Front. Chem.

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“…The functionalized DESs can chemically capture CO 2 and hold great promise for post-combustion capture. Interested readers can refer to anion-functionalized DESs like azolide-based DESs [14], superbase-based DESs like the mixture of biophenol-derived superbase ILs and ethylene glycol [15] and hydrophobic polyamine-based DESs [16].…”

Section: Introductionmentioning

confidence: 99%

Diffusivities and solubilities of carbon dioxide in deep eutectic solvents

Xin

Annaland

2023

Separation and Purification Technology

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“…It should be noted that many functionalized DESs can chemically capture CO 2 and hold great promise for postcombustion capture. Interested readers can refer to anion-functionalized DESs like azolide-based DESs., superbase-based DESs like the mixture of biophenol-derived superbase ILs and ethylene glycol, and hydrophobic polyamine-based DESs . The group contribution method (GCM) and the conductor-like screening model for real solvents (COSMO-RS) are recommended for the prediction of several of the important thermodynamic properties of solvents .…”

Section: Introductionmentioning

confidence: 99%

Development of Natural Hydrophobic Deep Eutectic Solvents for Precombustion CO₂ Capture

Xin

Gallucci

Annaland

2022

ACS Sustainable Chem. Eng.

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Hydrophobic deep eutectic solvents (DESs) have been designed as effective solvents for precombustion CO2 capture by using a conductor-like screening model for real solvents (COSMO-RS). Reliable CO2 solubilities in various compounds and binary solvents were estimated. We have developed new DESs from 38 selected, nature-derived, hydrophobic, and CO2 affinitive compounds. The possibilities of any two of these substances to form DESs were assessed from predicted activity coefficients, followed by an estimation of the CO2 solubilities of the theoretically feasible DESs. 58 promising hypothetical DESs were screened out. Subsequently, eight DESs were successfully prepared and characterized. Most of these DESs have a density larger than 1.0 g/mL at 298.15 K. The DESs have a similarly low volatility as decanoic acid–menthol (1:2) and are thermally stable below 420 K. Vanillin-4-oxoisophorone (1:3) and methyl salicylate-4-oxoisophorone (1:1) have been identified to be very promising for precombustion capture, showing comparable CO2 solubility and viscosity to the well-known, conventionally used Selexol solvent.

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Deep eutectic solvents composed of bio-phenol-derived superbase ionic liquids and ethylene glycol for CO₂ capture

Abstract: Deep eutectic solvents (DESs) formed by bio-phenol-derived superbase ionic liquids (ILs) and ethylene glycol (EG) perform a high CO2 capacity, up to 1.0 mol CO2/ mol DESs, which is much...

Cited by 39 publications

References 37 publications

Reviewing and screening ionic liquids and deep eutectic solvents for effective CO2 capture

Reviewing and screening ionic liquids and deep eutectic solvents for effective CO2 capture

Diffusivities and solubilities of carbon dioxide in deep eutectic solvents

Development of Natural Hydrophobic Deep Eutectic Solvents for Precombustion CO₂ Capture

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Deep eutectic solvents composed of bio-phenol-derived superbase ionic liquids and ethylene glycol for CO2 capture

Abstract: Deep eutectic solvents (DESs) formed by bio-phenol-derived superbase ionic liquids (ILs) and ethylene glycol (EG) perform a high CO2 capacity, up to 1.0 mol CO2/ mol DESs, which is much...

Cited by 39 publications

References 37 publications

Reviewing and screening ionic liquids and deep eutectic solvents for effective CO2 capture

Reviewing and screening ionic liquids and deep eutectic solvents for effective CO2 capture

Diffusivities and solubilities of carbon dioxide in deep eutectic solvents

Development of Natural Hydrophobic Deep Eutectic Solvents for Precombustion CO2 Capture

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Product

Resources

About

Deep eutectic solvents composed of bio-phenol-derived superbase ionic liquids and ethylene glycol for CO₂ capture

Development of Natural Hydrophobic Deep Eutectic Solvents for Precombustion CO₂ Capture