As the core component of the automobile braking system, brake pads have a complex structure and high failure rate. Their accurate and effective state monitoring can help to evaluate the safety performance of brake pads and avoid accidents caused by brake failure. The wear process of automobile brake pads is a gradual, nonlinear, and non-stationary time-varying system, and it is difficult to extract its features. Therefore, this paper proposes a CNN-LSTM brake pad wear state monitoring method. This method uses a Convolutional Neural Network (CNN) to complete the deep mining of brake pad wear characteristics and realize data dimensionality reduction, and a Long Short-Term Memory (LSTM) network to capture the time dependence of the brake pad wear sequence, so as to construct the nonlinear mapping relationship between brake pad wear characteristics and brake pad wear values. At the same time, the artificial Gorilla Troops Optimization (GTO) algorithm is used to perform multi-objective optimization of the network structure parameters in the CNN-LSTM model, and its powerful global search ability improves the monitoring effect of the brake pad wear status. The results show that the CNN-LSTM model based on GTO multi-objective optimization can effectively monitor the wear state of brake pads, and its coefficient of determination R2 value is 0.9944, the root mean square error RMSE value is 0.0023, and the mean absolute error MAE value is 0.0017. Compared with the BP model, CNN model, LSTM model, and CNN-LSTM model, the value of the coefficient of determination R2 is the closest to 1, which is increased by 8.29%, 5.52%, 4.47%, 3.30%, respectively, which can more effectively realize the monitoring and intelligent early warning of the brake pad wear state.