“…On cooling below the N-N TB transition (T = T NT B ), shrinkage in the pseudo-layer spacing (decreasing p 0 ) causes the pseudo-layer planes (planes of constant heliconical phase) to buckle, producing a striped optical texture and the appearance, at lower temperature or near the surfaces of untreated sample cells, of smectic-A-like focal conic defects. 7,19,29,30 As T → T NT B from above, the bend elastic constant decreases; if the "bare" splay to twist elastic constant ratio exceeds 2, a twist-bend modulation is favored at lower temperature 2 .…”