1991
DOI: 10.1063/1.460595
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Delayed ionization following photoexcitation of small clusters of refractory elements: Nanofilaments

Abstract: Dynamics of cluster dissociation following multiphoton ionization AIP Conf. Proc. 146, 483 (1986); 10.1063/1.35919 Delayed ionization following resonant photon absorption and intracluster electron transfer

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Cited by 58 publications
(43 citation statements)
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“…TE arises from internal conversion(s) to form the ground electronic state anion, which statistically detaches the excess electron over a long timescale (tens to hundreds of microseconds). 12,[22][23][24][25] The small contribution of TE in Fig. 3c for both CQ 0 and pBQ parallels the PD trend, which supports that the 3 2 [S] resonance acts as an intermediate state in the sequence of above-threshold relaxation dynamics to achieve the ground electronic state.…”
Section: This Journal Is © the Royal Society Of Chemistry 2015supporting
confidence: 65%
“…TE arises from internal conversion(s) to form the ground electronic state anion, which statistically detaches the excess electron over a long timescale (tens to hundreds of microseconds). 12,[22][23][24][25] The small contribution of TE in Fig. 3c for both CQ 0 and pBQ parallels the PD trend, which supports that the 3 2 [S] resonance acts as an intermediate state in the sequence of above-threshold relaxation dynamics to achieve the ground electronic state.…”
Section: This Journal Is © the Royal Society Of Chemistry 2015supporting
confidence: 65%
“…The PE signal in the lowest eKE window (< 0.1 eV) can be assigned to thermionic emission, corresponding to a statistical loss of electrons from hot vibrational ground state pBQ •-, [47][48][49][50] because the photodetachment cross section of an ideal anion falls to zero at threshold. 51,52 The broad peak centered around eKE ~0.4 eV is observed in all spectra with photon energies 2.5 < hv < 3.3 eV, although a small red-shift to eKE ~0.2 eV is observed around hv ~2.9 eV.…”
Section: Discussionmentioning
confidence: 99%
“…Experimental measurements of electron autodetachment processes have been carried out for small organic molecules [11][12][13][14] and atomic clusters [15,16]. In these measurements, electron detachment occurred after vibrational heating via multiphoton infrared absorption.…”
Section: ϫmentioning
confidence: 99%