Designed metal-organic framework composites for metal-ion batteries and metal-ion capacitors

Tatrari, Gaurav; An, Rong; Shah, Faiz Ullah

doi:10.1016/j.ccr.2024.215876

Cited by 12 publications

(1 citation statement)

References 296 publications

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“…By incorporating MOFs into composites with other substances, these properties can be enhanced, leading to improved functionalities and new applications. These properties can be further enhanced, leading to improved functionalities and new applications over the MOFs. − To date, several types of MOF composites, including polymer-MOFs, , nanoparticle-MOFs, MOF-membranes, and MOF-carbon composites, are available. These MOF composites have gained significant attention due to their tunable properties and versatile applications. − However, challenges and limitations remain in fabricating MOF composites that exhibit strong interactions with additional components, high stability, uniform coatings, maintaining structural integrity, and having well-controlled morphology.…”

Section: Introductionmentioning

confidence: 99%

Metal–Organic Framework on Fullerene (MOFOF) as a Hierarchical Composite by the Integration of Coordination Chemistry and Supramolecular Chemistry

Bhadra,

Shrestha,

et al. 2024

ACS Appl. Mater. Interfaces

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There is a synergy between coordination chemistry and supramolecular chemistry that has led to the development of innovative hierarchical composites with diverse functionalities. Here, we present a novel approach for the synthesis and characterization of a metal−organic framework on fullerene (MOFOF) composites, achieved through the integration of coordination chemistry and supramolecular chemistry principles. The hierarchical nature of the MOFOF harnesses the inherent properties of metal−organic frameworks and fullerenes. The two-step synthesis procedure involves controlled assembly of fullerenes as tube-like nanostructures (fullerene nanotube: FNT), their surface functionalization, and the on-surface growth of the MOF (in this case, ZIF-67). The method permits the precise tuning of morphology, effective distribution of MOF-on-FNT, and tight compositional control. The materials were comprehensively structurally characterized using electron microscopy, spectroscopic techniques, and other methods to elucidate the unique features and interactions within the MOFOF composites. The main findings reveal that the novel synthesis and characterization of MOFOF composites demonstrate the successful integration of coordination chemistry and supramolecular chemistry for the designing and fabricating of advanced hierarchical composites with tailored properties, including micro-and mesopore channels, interfacial facets, and defect sites. These properties are expected to lead to numerous potential applications such as gas storage and separation, catalysis, sensing, energy storage, and environmental remediation. However, only the capability of acid vapor sensing was tested and is described here.

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Section: Introductionmentioning

confidence: 99%

Metal–Organic Framework on Fullerene (MOFOF) as a Hierarchical Composite by the Integration of Coordination Chemistry and Supramolecular Chemistry

Bhadra,

Shrestha,

et al. 2024

ACS Appl. Mater. Interfaces

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Emerging Zinc‐Ion Capacitor Science: Compatible Principle, Design Paradigm, and Frontier Applications

Zhu,

Tai,

Liu

et al. 2024

Advanced Energy Materials

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The development of high energy/power density and long lifespan device is always the frontier direction and attracts great research attention in the energy storage fields. Zinc‐ion capacitors (ZICs), as an integration of zinc‐ion batteries and supercapacitors, have been widely regarded as one of the viable future options for energy storage, owing to their variable system assembly method and potential performance improvement. However, the research of ZICs still locate at initial stage until now, and how to construct the suitable systems for different condition is still challenging. Herein, the recent advance in the rational design of ZICs is reviewed in order to construct related theory including compatible principle and design paradigm. It starts with a systematically summary of the fundamental theory as well as the motivation. Then, the electrode materials are classified into capacitor‐type and battery‐type based on the storage mechanism, and the design strategies and progress of these two‐type candidates are comprehensively discussed, aiming to reveal the inherent relationship between the performance of devices and the component as well as architecture of electrode materials. Beyond that, the future perspectives in this emerging field are also given, expecting to guide the construction of high‐performance ZICs for practical applications and boost its development.

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Design and engineering of MOF/LDH hybrid nanocomposites and LDHs derived from MOF templates for electrochemical energy conversion/storage and environmental remediation: Mechanism and future perspectives

Abazari,

Sanati,

Fan

et al. 2025

Coordination Chemistry Reviews

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Designed metal-organic framework composites for metal-ion batteries and metal-ion capacitors

Cited by 12 publications

References 296 publications

Metal–Organic Framework on Fullerene (MOFOF) as a Hierarchical Composite by the Integration of Coordination Chemistry and Supramolecular Chemistry

Metal–Organic Framework on Fullerene (MOFOF) as a Hierarchical Composite by the Integration of Coordination Chemistry and Supramolecular Chemistry

Emerging Zinc‐Ion Capacitor Science: Compatible Principle, Design Paradigm, and Frontier Applications

Design and engineering of MOF/LDH hybrid nanocomposites and LDHs derived from MOF templates for electrochemical energy conversion/storage and environmental remediation: Mechanism and future perspectives

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