Determination of Rate Coefficient for Para-Orthohydrogen Conversion in Cryogenic Vortex Tube

Abstract

Raising efficiency of the cooling process for cryogenic hydrogen and minimizing hydrogen boil-off during storage and transportation of liquid hydrogen are critically important factors for widening implementation of hydrogen-based clean energy systems. One novel approach involves utilization of relatively simple catalyzed vortex tubes, where hydrogen in primarily para form is converted into ortho isomer while consuming a significant amount of heat. To design such systems effectively, better understanding is required about catalystassisted para-orthohydrogen conversion rates in high-speed vortical flows. In this study, a computational fluid dynamics simulation has been set up to model an experimental system with cryogenic hydrogen vortex tubes. Mesh-verification and validation study has been conducted first for a non-catalyzed tube. Then, the rate coefficient of the para-ortho conversion of cryogenic hydrogen has been determined by matching numerical results with experimental data available for a catalyzed vortex tube. The presented information can help design and optimize cryogenic hydrogen cooling devices with vortex tubes.