“…The developed bio-hybrid beads have elements on their structure like calcium (Ca 2+ ) and Lanthanum (La 3+ ) are also called Lewis acids. These Lewis acids interact with fluoride via electrostatic interaction 73 ( cf. Fig.…”
In this exploration, the promising hydroxyapatite (HAp) embedded La-BTC based metal organic frameworks (MOFs) substituted chitosan (CS) and alginate (Alg) namely HAp-La-BTC MOFs@Alg-CS hybrid beads were fabricated for effectual fluoride...
“…The developed bio-hybrid beads have elements on their structure like calcium (Ca 2+ ) and Lanthanum (La 3+ ) are also called Lewis acids. These Lewis acids interact with fluoride via electrostatic interaction 73 ( cf. Fig.…”
In this exploration, the promising hydroxyapatite (HAp) embedded La-BTC based metal organic frameworks (MOFs) substituted chitosan (CS) and alginate (Alg) namely HAp-La-BTC MOFs@Alg-CS hybrid beads were fabricated for effectual fluoride...
“…It is evident that the values of E from 8 to 16 kJ mol −1 manifest that both ligand exchange and electrostatic attraction are the mainly mechanism. 3,43,[45][46][47] To portray the affinity between the F − and the La(COOH) 3 , the dimensionless constant separation factor (R L ) values calculated according to the literature 21,37 decline quickly with the increasing of initial F − concentrations in the range of 10-80 mg L −1 and approach to zero, manifesting that the adsorbing system is encouraged at even higher F − concentrations (Fig. S1 †).…”
A La-based adsorbent was prepared with La(NO3)3·6H2O, 2-methylimidazole and DMF via amide-hydrolysis and used for fluoride decontamination from aqueous water.
“…The adsorbent stability and reproducibility are essential factors in determining the adsorption performance. 34 Especially in commercial applications, the reusability of the adsorbent is the key to reducing the cost. To regain PC-N with adsorption performance, the adsorbed PC-N was added to 100 mL of 1 mol L À1 NaOH solution, then placed on a magnetic stirrer, and desorbed at 300 rpm for 6 h. Afterward, the desorbed adsorbent was washed and dried in an oven at 100 1C for 24 h. The outcome results are shown in Fig.…”
Section: Regeneration Performance Of Pc-nmentioning
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