2002
DOI: 10.1006/jcis.2002.8233
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Development of a Constant Surface Pressure Penetration Langmuir Balance Based on Axisymmetric Drop Shape Analysis

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Cited by 33 publications
(35 citation statements)
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“…DINATEN© fits the experimental drop profiles, extracted from digital drop micrographs, to the Young-Laplace equation of capillarity by using Axisymmetric Drop Shape Analysis (ADSA), providing as outputs the drop volume V, the interfacial tension γ, and the interfacial area A. The adsorption process is recorded at constant interfacial area (30 mm 2 ) through a modulated fuzzy logic PID algorithm (proportional, integral, and derivative control) by changing the volume (Wege, Holgado-Terriza, & Cabrerizo-Vílchez, 2002). The drop is immersed in a glass cuvette (Hellma), which contains the oil phase and is kept in a thermostatized cell.…”
Section: Interfacial Tension Set-up and Subphase Exchange Techniquementioning
confidence: 99%
“…DINATEN© fits the experimental drop profiles, extracted from digital drop micrographs, to the Young-Laplace equation of capillarity by using Axisymmetric Drop Shape Analysis (ADSA), providing as outputs the drop volume V, the interfacial tension γ, and the interfacial area A. The adsorption process is recorded at constant interfacial area (30 mm 2 ) through a modulated fuzzy logic PID algorithm (proportional, integral, and derivative control) by changing the volume (Wege, Holgado-Terriza, & Cabrerizo-Vílchez, 2002). The drop is immersed in a glass cuvette (Hellma), which contains the oil phase and is kept in a thermostatized cell.…”
Section: Interfacial Tension Set-up and Subphase Exchange Techniquementioning
confidence: 99%
“…5,10 In these cases, the surface area of the droplet cannot be correlated with its volume using a simple spherical approximation. Meanwhile, the surface tension usually varies with the surface area at the presence of surfactants.…”
Section: Introductionmentioning
confidence: 99%
“…An instrumentation service is implemented that allows the remote operation of a pressure-controlled pendantdrop surface balance [20], which can be used to perform noninvasive surfactant adsorption kinetics studies at liquid-fluid interfaces at constant interfacial pressure. After a surfactant solution droplet is formed at the tip of a capillary by means of a microinjector, a measure of interfacial tension (or interfacial pressure, 21) and area (A) over time can be carried out by the instrument device maintaining a control ofthe drop area, drop volume or the interfacial pressure.…”
Section: Resultsmentioning
confidence: 99%