2013
DOI: 10.1016/j.jlumin.2013.02.007
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Development of Dy3+ activated K2MgP2O7 pyrophosphate phosphor for energy saving lamp

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Cited by 41 publications
(10 citation statements)
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“…[43][44][45] Similarly the dominant blue emission is observed for the Dy 3+ ions occupying the inversion site in GdPO 4 , K 2 MgP 2 O 7 and GdFeO 3 phosphor. [46][47][48] In case of Gd 2 O 3 , a sesquioxides with cubic bixbyite structure (Ia 3) have crystallographically two nonequivalent cationic sites with 6-fold coordination namely C 2 non-inversion symmetry with Gd 3+ in the centre of a distorted cube with two oxygen vacancies on the face diagonal and S 6 site symmetry with inversion symmetry resulting from two oxygen vacancies lying on one body diagonal. 49 The photoluminescence properties varies with the site preference.…”
Section: Resultsmentioning
confidence: 99%
“…[43][44][45] Similarly the dominant blue emission is observed for the Dy 3+ ions occupying the inversion site in GdPO 4 , K 2 MgP 2 O 7 and GdFeO 3 phosphor. [46][47][48] In case of Gd 2 O 3 , a sesquioxides with cubic bixbyite structure (Ia 3) have crystallographically two nonequivalent cationic sites with 6-fold coordination namely C 2 non-inversion symmetry with Gd 3+ in the centre of a distorted cube with two oxygen vacancies on the face diagonal and S 6 site symmetry with inversion symmetry resulting from two oxygen vacancies lying on one body diagonal. 49 The photoluminescence properties varies with the site preference.…”
Section: Resultsmentioning
confidence: 99%
“…(Fig. 6) manifests sharp f-f fluorescent transition of Dy 3+ around the range of 300-400 nm.The different excitation peaks observed at 325 nm, 352 nm, 365 nm and 387 nm are attributed to transitions from ground state 6 H 15/2 to the higher excited states 6 P 3/2 , 6 P 7/2 , 6 P 5/2 , 4 K 17/2 , respectively [29]. However, maximum PL intensity is found for 352 nm excitation wavelength.…”
Section: Photoluminescence Investigationsmentioning
confidence: 89%
“…In particular, their applications as LED devices can help in replacing argon-mercury discharge fluorescent lamps, which are extensively used for general lighting purposes. They can also be applied as alternative mercury-free excitation sources for avoiding the use of hazardous ingredients and environmentally unsafe materials [20]. Moreover, they have been recently demonstrated as solar cell materials and high upconversion luminescent materials [21,22].…”
Section: Introductionmentioning
confidence: 99%