Development of thin film composite for CO<sub>2</sub> separation in membrane gas absorption application

Ahmad, A.L.; Sunarti, Abd Rahman; Teong, Lee Keat; Fernando, W.J.N.

doi:10.1002/apj.339

Cited by 7 publications

(3 citation statements)

References 21 publications

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“…117 There are adsorption-selective NPCFs that separate the components of a gas mixture depending on their adsorption properties, and size-and shape-selective NPCFs that separate the components of a gas mixture depending on their pore sizes and shapes. [118][119][120][121][122][123] It was reported that NPCFs had high separation performance for air and for organic vapors of low molecular weight as well as for the dehydrogenation of cyclohexane to benzene. 124,125 For air separation, NPCFs performed well in terms of the ideal selectivity ratio for oxygen to nitrogen permeances of $3 to 6 and the oxygen permeance of 108 mol m À2 s À1 Pa À1 and in terms of relative insensitivity to operating temperature.…”

Section: Separation Membranesmentioning

confidence: 99%

Recent progress in the synthesis and applications of nanoporous carbon films

et al. 2011

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The synthesis and applications of thin nanoporous carbon films or membranes (NPCFs) are outlined with a focus on recent literature examples. NPCFs have large specific surface area, high electrical and thermal conductivity and both chemical and mechanical stability properties that facilitate increasing conventional uses in purification and separation, adsorption, and catalysis. They have potential applications in nanodevices, supercapacitors, lithium ion batteries, and chemical and bio-sensors. We summarize the various NPCF fabrication techniques, including solid-or soft-templating, direct pyrolysis on porous organic polymer precursors, chemical or physical vapor deposition and electrochemical deposition, and highlight the future design trends in the fabrication of NPCFs with ordered nanopore structures.

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Section: Separation Membranesmentioning

confidence: 99%

Recent progress in the synthesis and applications of nanoporous carbon films

et al. 2011

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“…Temperature and feed pressure were controlled with an error of +/-0.1°C and 0.1 bar using MKS instrument temperature and feed pressure controllers, respectively. The gas permeation was calculated using equation (1), while ideal selectivity was calculated using equation (2) as follows [22,23].…”

Section: Permeation Studymentioning

confidence: 99%

Separation of CO₂ from Small Gas Molecules Using Deca-Dodecasil 3 Rhombohedral (DDR3) Membrane Synthesized via Ultrasonically Assisted Hydrothermal Growth Method

Mubashir

Fong

Saqib

et al. 2020

Advances in Polymer Technology

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Deca-dodecasil 3 rhombohedral (DDR3) membrane has received much attention in CO2 separation from small gas molecules because of its molecular sieving property and stable characteristics. Therefore, the present work is focusing on the utilization of previously fabricated membrane (synthesized in 3 days as reported in our previous work) to study the effect of hydrocarbons and its durability at the previously optimized conditions. Subsequently, gas permeation study was conducted on the DDR3 membrane in CO2 separation from small gas molecules and it was found that the permeance of H2, CO2, N2, and CH4 decreased in the order of H2 > CO2 > N2 > CH4, according to the increase in kinetic diameter of these gas molecules. Besides, it was observed that the ideal selectivities of the gas pairs decreased in the sequence of CO2/CH4 > CO2/N2 > H2/CO2. On the other hand, it was found that the presence of hydrocarbon impurities in the gas mixture containing CO2 and CH4 has directly affected the performance of DDR3 membrane and contributed to the losses of CO2 permeability, CH4 permeability, and CO2/CH4 selectivity of 39.1%, 14.8%, and 4.2%, respectively. Consequently, from the stability test, the performance of DDR3 membrane remained stable for 96 h, even after the separation testing using CO2 and CH4 gas mixture containing hydrocarbon impurities.

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“…A range of technologies to mitigate climate change by isolating a significant fraction of CO 2 from the atmosphere are pursued . The calcium looping technology for CO 2 capture in the context of continued utilization of coal in power plants is known as one promising technology .…”

Section: Introductionmentioning

confidence: 99%

Cyclic CO₂ capture of carbide slag modified by pyroligneous acid in calcium looping cycles

Liu

Sun

et al. 2014

Asia-Pacific J Chem Eng

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Carbide slag is a kind of industrial waste obtained in the production of acetylene that is the raw material of polyvinyl chloride in chlor-alkali plants. The carbide slag modified by pyroligneous acid was proposed as a CO 2 sorbent at high temperature. The CO 2 capture capacity of the carbide slag modified by pyroligneous acid in the calcium looping cycles was investigated in a thermogravimetric analyzer and a dual fixed-bed reactor. The modified carbide slag exhibits better CO 2 capture capacity than the carbide slag. The modified carbide slag releases the organic substances whose combustion leads to a drop in CO 2 capture capacity. The pre-calcination treatment of the modified carbide slag at 400°C before the first calcination was employed to avoid the combustion of the organic substances. The pre-calcined modified carbide slag exhibits higher carbonation conversions, compared with the modified carbide slag without pre-calcination treatment. The pre-calcined modified carbide slag achieves higher carbonation conversions at 950°C and shows larger surface area and pore volume than the modified carbide slag in the cycles. It indicates that combining the modification by pyroligneous acid with the pre-calcination treatment apparently improves cyclic CO 2 capture capacity of the carbide slag in the multiple cycles.

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Development of thin film composite for CO₂ separation in membrane gas absorption application

Cited by 7 publications

References 21 publications

Recent progress in the synthesis and applications of nanoporous carbon films

Recent progress in the synthesis and applications of nanoporous carbon films

Separation of CO₂ from Small Gas Molecules Using Deca-Dodecasil 3 Rhombohedral (DDR3) Membrane Synthesized via Ultrasonically Assisted Hydrothermal Growth Method

Cyclic CO₂ capture of carbide slag modified by pyroligneous acid in calcium looping cycles

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Development of thin film composite for CO2 separation in membrane gas absorption application

Cited by 7 publications

References 21 publications

Recent progress in the synthesis and applications of nanoporous carbon films

Recent progress in the synthesis and applications of nanoporous carbon films

Separation of CO2 from Small Gas Molecules Using Deca-Dodecasil 3 Rhombohedral (DDR3) Membrane Synthesized via Ultrasonically Assisted Hydrothermal Growth Method

Cyclic CO2 capture of carbide slag modified by pyroligneous acid in calcium looping cycles

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Development of thin film composite for CO₂ separation in membrane gas absorption application

Separation of CO₂ from Small Gas Molecules Using Deca-Dodecasil 3 Rhombohedral (DDR3) Membrane Synthesized via Ultrasonically Assisted Hydrothermal Growth Method

Cyclic CO₂ capture of carbide slag modified by pyroligneous acid in calcium looping cycles