2020
DOI: 10.26434/chemrxiv.11914377.v1
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DFT Calculations Investigate Competing Pathways to Form Dimeric Neopentylpalladium(II) Amido Complexes

Abstract: Computational methods were utilized to study the formation of a dimeric neopentylpalladium(II) amido complex (D). The dimeric core of D contains asymmetric bridging of the anilide groups. Electron density analyses indicate that each palladium center of D forms a dative bond to the nitrogen trans to the coordinated phosphine, while the bond to the nitrogen cis to the phosphine lies closer to the covalent regime. Analysis of the structure of D was corroborated by study of the frontier orbitals and the energetics… Show more

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