2008
DOI: 10.1002/zaac.200700484
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Dichalcogenide Cleavage and Carbonyl Insertion Reactions on a Dirhodium Bond

Abstract: The reaction of the binuclear rhodium complex [(ηϪC 5 H 5 ) 2 Rh 2 (μ-CO)(μ-η 1 :η 1 -C 2 (CF 3 ) 2 )] with a series of dichalcogenides, R 2 E 2 (E ϭ S, Se, Te; R ϭ Me, Et, i-Pr, Ph, Fc; not all combinations) has provided mixtures of complexes, the majority of which have been characterized by standard spectroscopic techniques. These complexes arise as a consequence of carbonyl substitution followed by chalcogen-chalcogen bond cleavage giving [(675 (E ϭ Se, Te; R ϭ Me, Et, i-Pr, Ph, Fc; not all combinations). I… Show more

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