2024
DOI: 10.1021/acs.inorgchem.4c00545
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Dimensional Reduction of Metal–Organic Frameworks for Photocatalytic Synthesis of Fused Tetracyclic Heterocycles

Xiao Feng,
Yanwei Ren,
Haosen Wang
et al.

Abstract: Heterogeneous palladium catalysts with high efficiency, high Pd atom utilization, simplified separation, and recycle have attracted considerable attention in the field of synthetic chemistry. Herein, we reported a zirconium-based two-dimensional metal−organic framework (2D-MOF)-based Pd(II) photocatalyst (Zr−Ir−Pd) by merging the Ir photosensitizers and Pd(II) species into the skeletons of the 2D-MOF for the Pd(II)-catalyzed oxidation reaction. Morphological and structural characterization identified that Zr−I… Show more

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