Dimethyl sulfoxide as a function additive on halogen-free electrolyte for magnesium battery application

Gamal, R.; Sheha, E.; Kholy, M. M. El

doi:10.1039/d3ra01707a

Cited by 2 publications

(2 citation statements)

References 44 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The addition of DMSO to the electrolyte changes the interfacial structure of the Mg anode/electrolyte and promotes ion transfer. [114] However, further optimization and compatibility with cathodes are expected to be carried out in future work.…”

Section: Chlorine-free Electrolytementioning

confidence: 99%

“…reported an electrolyte based on Mg(NO 3 ) 2 , Mg(OTf) 2 and SN dissolved in ACN/G4 cosolvents, with dimethyl sulfoxide (DMSO) as a functional additive. The addition of DMSO to the electrolyte changes the interfacial structure of the Mg anode/electrolyte and promotes ion transfer [114] . However, further optimization and compatibility with cathodes are expected to be carried out in future work.…”

Section: Application and Improvement Strategies Of Mg(otf)2‐based Ele...mentioning

confidence: 99%

See 1 more Smart Citation

The Metamorphosis of Mg(SO₃CF₃)₂‐based Electrolytes for Rechargeable Magnesium Batteries

Chen,

Tan,

et al. 2024

ChemElectroChem

View full text Add to dashboard Cite

Cost‐effective, non‐corrosive and non‐nucleophilic Mg(SO3CF3)‐based electrolytes with high anodization stability are promising candidates for realizing high‐performance rechargeable magnesium batteries (RMBs). Since the 1990s, the community has developed polymer‐based, room‐temperature molten salt‐based, chlorine‐containing and chlorine‐free electrolyte systems using Mg(SO3CF3)2 as the simple magnesium salt. However, there is currently a lack of overall understanding of the metamorphosis of Mg(SO3CF3)2‐based electrolytes. This survey reviews the development of various branches of Mg(SO3CF3)2‐based electrolytes, with a special focus on strategies to improve electrolyte performance. First, the utilization of various polymer matrices, room‐temperature molten salts, inorganic/organic chlorine salts and chelating ligands to promote the performance of Mg(SO3CF3)2‐based (quasi‐)solid and liquid electrolytes is outlined. Subsequently, combining the passivation nature of Mg(SO3CF3)2 and polar aprotic solvents toward the Mg anode and the current improvement strategies, the future challenges and opportunities of Mg(SO3CF3)2‐based electrolytes in various branches are discussed. These summaries and discussions will provide guidelines for the development of Mg(SO3CF3)2‐based electrolytes with desirable properties for RMBs.

show abstract

Section: Chlorine-free Electrolytementioning

confidence: 99%

Section: Application and Improvement Strategies Of Mg(otf)2‐based Ele...mentioning

confidence: 99%

The Metamorphosis of Mg(SO₃CF₃)₂‐based Electrolytes for Rechargeable Magnesium Batteries

Chen,

Tan,

et al. 2024

ChemElectroChem

View full text Add to dashboard Cite

show abstract

Thermal Stability and Electrical Conductivity of Polyvinyl Alcohol Composites Reinforced with Mn₂O₃–rGO

Gamal,

Soliman,

Khalid

2025

ChemistrySelect

View full text Add to dashboard Cite

The current work is concerned with the study and examination of the thermal and electrical characteristics of polyvinyl alcohol (PVA)/Mn2O3–reduced graphene oxide (rGO) nanocomposite. The Mn2O3–rGO composite was synthesized using a hydrothermal approach technique, and then PVA films were strengthened with varying amounts of Mn2O3–rGO nanoparticles (NP) prepared by the casting method. Raman analysis was applied to polymer films to ensure the complexation between the PVA and Mn2O3–rGO. Thermogravimetric analysis (TGA) and electrical analysis are used to investigate the effect of Mn2O3–rGO NP on the thermal stability and electrical conductivity of the polymer films. The films' thermal stability was raised by increasing the Mn2O3–rGO content in the PVA matrix. The polymer films exhibit an increase in electrical conductivity from 2.023 × 10⁻⁸ S·cm⁻¹ for pure PVA to 1.895 × 10⁻⁵ S·cm⁻¹ for PVA‐1.5% Mn2O3–rGO, which arises from the rise in free charge carrier mobility and hopping ionic hopping. Furthermore, in accordance with the Arrhenius relation, conductivity increases with temperature. The results nominated the present composite in flexible electronic applications.

show abstract

Dimethyl sulfoxide as a function additive on halogen-free electrolyte for magnesium battery application

Abstract: In this study, we design a functional halogen-free electrolyte by linking its active species with a high polarity dimethyl sulfoxide to reduce the solvation barrier of Mg2+.

Cited by 2 publications

References 44 publications

The Metamorphosis of Mg(SO₃CF₃)₂‐based Electrolytes for Rechargeable Magnesium Batteries

The Metamorphosis of Mg(SO₃CF₃)₂‐based Electrolytes for Rechargeable Magnesium Batteries

Thermal Stability and Electrical Conductivity of Polyvinyl Alcohol Composites Reinforced with Mn₂O₃–rGO

Contact Info

Product

Resources

About

Dimethyl sulfoxide as a function additive on halogen-free electrolyte for magnesium battery application

Abstract: In this study, we design a functional halogen-free electrolyte by linking its active species with a high polarity dimethyl sulfoxide to reduce the solvation barrier of Mg2+.

Cited by 2 publications

References 44 publications

The Metamorphosis of Mg(SO3CF3)2‐based Electrolytes for Rechargeable Magnesium Batteries

The Metamorphosis of Mg(SO3CF3)2‐based Electrolytes for Rechargeable Magnesium Batteries

Thermal Stability and Electrical Conductivity of Polyvinyl Alcohol Composites Reinforced with Mn2O3–rGO

Contact Info

Product

Resources

About

The Metamorphosis of Mg(SO₃CF₃)₂‐based Electrolytes for Rechargeable Magnesium Batteries

The Metamorphosis of Mg(SO₃CF₃)₂‐based Electrolytes for Rechargeable Magnesium Batteries

Thermal Stability and Electrical Conductivity of Polyvinyl Alcohol Composites Reinforced with Mn₂O₃–rGO