Dinuclear Iron, Cobalt and Uranium Complexes of New Diamidoether Ligands

Leznoff, Daniel B.; Mund, Garry; Jantunen, Kimberly C.; Bhatia, Purvi H.; Gabert, Andrea J.; Batchelor, Raymond J.

doi:10.1080/00223131.2002.10875493

Cited by 18 publications

(21 citation statements)

References 6 publications

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“…The dipotassium salt, K 2 [(NON Ar )(THF) n ] ( 1 ), is readily obtained from the reaction of KH with the ligand pre-cursor (NON Ar )H 2 19. NMR analysis of the freshly prepared salt is consistent with incorporation of a single molecule of THF ( n = 1), and the reagent can be used without further purification.…”

Section: Resultsmentioning

confidence: 99%

Reduction of organic azides by indyl-anions. Isolation and reactivity studies of indium–nitrogen multiple bonds

2019

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Section: Resultsmentioning

confidence: 99%

Reduction of organic azides by indyl-anions. Isolation and reactivity studies of indium–nitrogen multiple bonds

2019

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“…A C 6 D 6 solution of 2 . under the same conditions shows the onset of decomposition within 24 h, indicated by gradual decolorizing of the solution and concomitant formation of a solid precipitate; the major diamagnetic species formed in solution during this decomposition was the neutral ligand (NON Ar )H 2 18…”

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confidence: 91%

Isolation and Characterization of a Bismuth(II) Radical

et al. 2015

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“…Elemental analyses were performed by S. Boyer at London Metropolitan University. (NON R )H 2 were synthesised according to literature procedures [7c,f,14a,21] . All other reagents were purchased from Sigma‐Aldrich and used without further purification.…”

Section: Methodsmentioning

confidence: 99%

Synthesis of HeavyN‐Heterocyclic Tetrylenes: Influence of Ligand Sterics on Structure

et al. 2021

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The synthesis and structural characterisation of [(NONR)M] (NON=O(SiMe2NR)2]2−; R=tBu, Ph, 2,6‐Me2C6H3 (Dmp), 2,6‐iPr2C6H3 (Dipp); M=Ge, Sn, Pb) is described. Germanium complexes [(NONPh)Ge], [(NONDmp)Ge] and [(NONDipp)Ge] are monomeric. Tin complexes [(NONPh)Sn]2, [(NONDmp)Sn]2 and [(NONtBu)Sn]2 are dimeric in the solid‐state, with [(NONPh)Sn]2 forming a link through bridging N‐atoms, [(NONDmp)Sn]2 linked through Sn⋅⋅⋅Ar contacts and [(NONtBu)Sn]2 forming the first distannene bearing two amido ligands. In contrast, [(NONDipp)Sn] is monomeric in the solid‐state. The lead complexes [(NONPh)Pb]2 and [(NONDmp)Pb]2 are isostructual with their tin analogues while [(NONtBu)Pb] is monomeric in the solid‐state. Solution phase NMR spectroscopic data suggest that all [(NONR)M] compounds are monomeric in solution. Structural parameters, including buried volume (%Vbur) are discussed.

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Dinuclear Iron, Cobalt and Uranium Complexes of New Diamidoether Ligands

Cited by 18 publications

References 6 publications

Reduction of organic azides by indyl-anions. Isolation and reactivity studies of indium–nitrogen multiple bonds

Reduction of organic azides by indyl-anions. Isolation and reactivity studies of indium–nitrogen multiple bonds

Isolation and Characterization of a Bismuth(II) Radical

Synthesis of HeavyN‐Heterocyclic Tetrylenes: Influence of Ligand Sterics on Structure

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