A Tm, Mg co doped LiTaO 3 crystal has been grown by Czochralski method. Room temperature polarized absorption spectra and fluorescence spectrum of the Tm, Mg:LiTaO 3 crystal were measured and analyzed. The maximum absorption cross section is 6.0791 × 10 -20 cm 2 at around 790 nm with full width at half maximum of 5 nm. The emission cross section of 3 F 4 manifold was 2.2 × 10 -20 cm 2 . The spectroscopic parameters of Tm 3+ ion were calculated by applying the Judd-Ofelt approach, and the intensity parameters Ω 2 , Ω 4 , and Ω 6 were obtained to be 7.71 × 10 -20 , 1.09 × 10 -20 , and 1.16 × 10 -20 cm 2 , respectively. The branch ing ratios and radiative lifetimes were also presented and the radiative lifetime of Tm 3+ 3 F 4 3 H 6 transition is 968.3 μs. The results were also analyzed and compared with other Tm 3+ doped hosts.